Supramolecular aggregation of a redox-active copper-naphthalenediimide network with intrinsic electron conduction

被引：56

作者：

Kuang, Xiaofei ^{[1
,2
,3
]}

Chen, Shanci ^{[2
,3
]}

Meng, Lingyi ^{[1
,2
,3
]}

Chen, Jing ^{[1
,2
,3
]}

Wu, Xiaoyuan ^{[2
,3
]}

Zhang, Guanhua ^{[2
,3
]}

Zhong, Guiming ^{[1
,2
,3
]}

Hu, Ting ^{[1
,2
,3
]}

Li, Yuhang ^{[1
,2
,3
]}

Lu, Can-Zhong ^{[1
,2
,3
]}

机构：

[1] Chinese Acad Sci, Haixi Inst, Xiamen Inst Rare Earth Mat, Xiamen 361021, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China

[3] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 11期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORK; CHARGE-TRANSFER; THIN-FILM; CHEMISTRY; EFFICIENT;

D O I：

10.1039/c8cc10269d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A sextuple ordered interpenetrated copper-naphthalenediimide network has been constructed by combining the features of porous metal-organic frameworks and pi-conjugated supramolecular aggregation. The material exhibits intrinsic semiconductive features with narrow bandgap energy (1.2 eV) and outstanding electron transport. Theoretical calculations combined with experiments indicate that the high electron conduction may originate from pi-d coupling and J-aggregation.

引用

页码：1643 / 1646

页数：4

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