Experimental investigation of combustion of a gasless pelletized mixture of Ti+0.5C in argon and nitrogen coflows

被引:20
作者
Seplyarskii, B. S. [1 ]
Tarasov, A. G. [1 ]
Kochetkov, R. A. [1 ]
机构
[1] Russian Acad Sci, Inst Struct Macrokinet & Problems Mat Sci, Chernogolovka 142432, Russia
基金
俄罗斯基础研究基金会;
关键词
mixture of Ti+0.5C; pelletized composition; combustion modes; burning rate; PROPAGATION; MACROKINETICS; MECHANISM; SYSTEM; CARBON;
D O I
10.1134/S0010508213050079
中图分类号
O414.1 [热力学];
学科分类号
摘要
Combustion of a pelletized mixture of titanium and carbon black placed in a quartz tube and exposed to a flow of argon or nitrogen is studied. The gas flow (cocurrent filtration) is provided by a fixed pressure gradient at the inlet and outlet of the tube, which did not exceed 1 atm. The possible modes of combustion of pelletized mixtures related to the presence of a more complex hierarchy of scales (micro, macro, and meso) compared to that of powder mixtures (micro, macro) are analyzed. A comparison is made of the burning rates of powder and pelletized mixtures. An increase in the burning rate when using pelletized mixtures was found experimentally. It is shown that the gas coflow through the pelletized mixture of Ti + 0.5C leads to an increase in the burning rate. It is established that the propagation of the flame front of the pelletized mixture of Ti + 0.5C in flows of nitrogen and argon is controlled by different reactions. In contrast to combustion of powder mixtures of Ti + 0.5C, in combustion of pelletized mixtures of Ti + 0.5C in a nitrogen flow, only one front is observed. It is proved that radiation plays a significant role in the propagation of the combustion front in the pelletized mixture of Ti + 0.5C.
引用
收藏
页码:555 / 562
页数:8
相关论文
共 34 条
  • [1] ALDUSHIN AP, 1978, DOKL AKAD NAUK SSSR+, V241, P72
  • [2] Amosov A.P., 2007, Powder Technology of Self-Propagating High-Temperature Synthesis of Materials
  • [3] AMOSOV AP, 2011, IZV VYSSH UCHEBN ZAV, P30
  • [4] [Anonymous], 1998, PHYS ENCY, V5
  • [5] AVAKYAN AB, 1975, COMBUSTION PROCESSES, P98
  • [6] BADALYAN VE, 1984, PRODUCTION USE POLYV
  • [7] BELYAEV AF, 1973, TRANSITION COMBUSTIO, V1, P32
  • [8] Microstructural and mechanical characterization of titanium nitride produced by SHS
    Carole, D
    Fréty, N
    Etienne-Calas, S
    Merlet, C
    Marin-Ayral, RM
    [J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2006, 419 (1-2): : 365 - 371
  • [9] DEGREVE J, 1987, MAT PROCESS SHS, P247
  • [10] Deich M., 1961, Technical gas dynamic