One-dimensional heteropolynuclear tetracyanopalladate(II) complexes: Syntheses, crystal structures, thermal analyses and spectroscopic investigations

被引：5

作者：

Aksel, Mehran ^{[1
]}

Kurkcuoglu, Gunes Suheyla ^{[2
]}

Yesilel, Okan Zafer ^{[3
]}

Buyukgungor, Orhan ^{[4
]}

机构：

[1] Eskisehir Osmangazi Univ, Inst Sci, Dept Phys, TR-26480 Eskisehir, Turkey

[2] Eskisehir Osmangazi Univ, Fac Arts & Sci, Dept Phys, TR-26480 Eskisehir, Turkey

[3] Eskisehir Osmangazi Univ, Fac Arts & Sci, Dept Chem, TR-26480 Eskisehir, Turkey

[4] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Phys, TR-55139 Samsun, Turkey

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2014年 / 1059卷

关键词：

Heterometallic complexes; Cyano bridged complexes; Tetracyanopalladate(II) complexes; N; N-diethylethylenediamine complexes; BRIDGED BIMETALLIC COMPLEXES; MAGNETIC-PROPERTIES; TETRACYANONICKELATE(II); CU(II);

D O I：

10.1016/j.molstruc.2013.11.006

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Three new complexes, [Ni(deten)(2)Pd(mu-CN)(2)(CN)(2)](n) (1), [Zn(deten)(2)Pd(mu-CN)(2)(CN)(2)](n) (2) and [Cd(deten)(2)Pd(mu-CN)(2)(CN)(2)](n) (3) (deten = N,N-diethylethylenediamine), have been synthesized and characterized by elemental, spectral (FT-IR and Raman) and thermal analysis techniques. The crystal structures of the complexes 2 and 3 have been determined by X-ray single crystal diffraction. The crystallographic analysis reveals that they crystallize in the monoclinic system, space group P2(1)/c. The Pd(II) atom is coordinated by four cyano groups. The M(II) atom is also surrounded by the two symmetry related deten ligands and the two symmetry related N atom of cyano groups. A possible decomposition of the complexes was investigated in the temperature range 30-700 degrees C in static air. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：101 / 107

页数：7

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