Functionalized Polymers from Lignocellulosic Biomass: State of the Art

被引：55
作者：
Ten, Elena
Vermerris, Wilfred [1 ]
机构：
[1] Univ Florida, Dept Microbiol & Cell Sci, Gainesville, FL 32610 USA
来源：
POLYMERS | 2013年 / 5卷 / 02期
基金：
美国食品与农业研究所;
关键词：
biomass; cell wall; cellulose; hemicellulose; lignin; nanotechnology; polymer; GRAFTED CELLULOSE NANOWHISKERS; ENZYME-ASSISTED PREPARATION; MICROFIBRILLATED CELLULOSE; CARBON NANOTUBES; MECHANICAL-PROPERTIES; LIGNIN BIOSYNTHESIS; PHYSICAL-PROPERTIES; POLYELECTROLYTE MULTILAYERS; ETHANOL-PRODUCTION; BARRIER PROPERTIES;
D O I：
10.3390/polym5020600
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Since the realization that global sustainability depends on renewable sources of materials and energy, there has been an ever-increasing need to develop bio-based polymers that are able to replace petroleum-based polymers. Research in this field has shown strong potential in generating high-performance functionalized polymers from plant biomass. With the anticipated large-scale production of lignocellulosic biomass, lignin, cellulose and hemicellulosic polysaccharides will be abundantly available renewable feedstocks for biopolymers and biocomposites with physico-chemical properties that match or exceed those of petroleum-based compounds. This review examines the state of the art regarding advances and challenges in synthesis and applications of specialty polymers and composites derived from cellulose, hemicellulose and lignin, ending with a brief assessment of genetic modification as a route to tailor crop plants for specific applications.
引用
收藏
页码：600 / 642
页数：43
相关论文
共 259 条
[61]   The influence of the chemical and structural features of xylan on the physical properties of its derived hydrogels [J].
Fonseca Silva, Teresa Cristina ;
Habibi, Youssef ;
Colodette, Jorge Luiz ;
Lucia, Lucian A. .
SOFT MATTER, 2011, 7 (03) :1090-1099
[62]   Effects of modified cellulose nanocrystals on the barrier and migration properties of PLA nano-biocomposites [J].
Fortunati, E. ;
Peltzer, M. ;
Armentano, I. ;
Torre, L. ;
Jimenez, A. ;
Kenny, J. M. .
CARBOHYDRATE POLYMERS, 2012, 90 (02) :948-956
[63]   Reinforcement of Polymeric Submicrometer-sized Fibers by Microfibrillated Cellulose [J].
Fortunato, Giuseppino ;
Zimmermann, Tanja ;
Luebben, Joern ;
Bordeanu, Nico ;
Hufenus, Rudolf .
MACROMOLECULAR MATERIALS AND ENGINEERING, 2012, 297 (06) :576-584
[64]   Comparison of molecular weight and molecular weight distributions of softwood and hardwood lignosulfonates [J].
Fredheim, GE ;
Braaten, SM ;
Christensen, BE .
JOURNAL OF WOOD CHEMISTRY AND TECHNOLOGY, 2003, 23 (02) :197-215
[65]   Genetic manipulation of lignin reduces recalcitrance and improves ethanol production from switchgrass [J].
Fu, Chunxiang ;
Mielenz, Jonathan R. ;
Xiao, Xirong ;
Ge, Yaxin ;
Hamilton, Choo Y. ;
Rodriguez, Miguel, Jr. ;
Chen, Fang ;
Foston, Marcus ;
Ragauskas, Arthur ;
Bouton, Joseph ;
Dixon, Richard A. ;
Wang, Zeng-Yu .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2011, 108 (09) :3803-3808
[66]   Alteration in Lignin Biosynthesis Restricts Growth of Fusarium spp. in Brown Midrib Sorghum [J].
Funnell-Harris, Deanna L. ;
Pedersen, Jeffrey F. ;
Sattler, Scott E. .
PHYTOPATHOLOGY, 2010, 100 (07) :671-681
[67]   Interfacial adhesion improvement of plain woven carbon fiber reinforced epoxy filled with micro-fibrillated cellulose by addition liquid rubber [J].
Gabr, Mohamed H. ;
Abd Elrahman, Mostafa ;
Okubo, Kazuya ;
Fujii, Toru .
JOURNAL OF MATERIALS SCIENCE, 2010, 45 (14) :3841-3850
[68]   Effect of microfibrillated cellulose on mechanical properties of plain-woven CFRP reinforced epoxy [J].
Gabr, Mohamed H. ;
Elrahman, Mostafa Abd ;
Okubo, Kazuya ;
Fujii, Toru .
COMPOSITE STRUCTURES, 2010, 92 (09) :1999-2006
[69]   Effect of fatty acids on the structure and performance of cellulose acetate nanofiltration membranes in retention of nitroaromatic pesticides [J].
Ghaemi, Negin ;
Madaeni, Sayed S. ;
Alizadeh, Abdolhamid ;
Rajabi, Hamid ;
Daraei, Parisa ;
Falsafi, Monir .
DESALINATION, 2012, 301 :26-41
[70]   Separation of nitrophenols using cellulose acetate nanofiltration membrane: Influence of surfactant additives [J].
Ghaemi, Negin ;
Madaeni, Sayed S. ;
Alizadeh, Abdolhamid ;
Daraei, Parisa ;
Zinatizadeh, Ali Akbar ;
Rahimpour, Farshad .
SEPARATION AND PURIFICATION TECHNOLOGY, 2012, 85 :147-156
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