Functionalized Polymers from Lignocellulosic Biomass: State of the Art

被引:55
作者
Ten, Elena
Vermerris, Wilfred [1 ]
机构
[1] Univ Florida, Dept Microbiol & Cell Sci, Gainesville, FL 32610 USA
基金
美国食品与农业研究所;
关键词
biomass; cell wall; cellulose; hemicellulose; lignin; nanotechnology; polymer; GRAFTED CELLULOSE NANOWHISKERS; ENZYME-ASSISTED PREPARATION; MICROFIBRILLATED CELLULOSE; CARBON NANOTUBES; MECHANICAL-PROPERTIES; LIGNIN BIOSYNTHESIS; PHYSICAL-PROPERTIES; POLYELECTROLYTE MULTILAYERS; ETHANOL-PRODUCTION; BARRIER PROPERTIES;
D O I
10.3390/polym5020600
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Since the realization that global sustainability depends on renewable sources of materials and energy, there has been an ever-increasing need to develop bio-based polymers that are able to replace petroleum-based polymers. Research in this field has shown strong potential in generating high-performance functionalized polymers from plant biomass. With the anticipated large-scale production of lignocellulosic biomass, lignin, cellulose and hemicellulosic polysaccharides will be abundantly available renewable feedstocks for biopolymers and biocomposites with physico-chemical properties that match or exceed those of petroleum-based compounds. This review examines the state of the art regarding advances and challenges in synthesis and applications of specialty polymers and composites derived from cellulose, hemicellulose and lignin, ending with a brief assessment of genetic modification as a route to tailor crop plants for specific applications.
引用
收藏
页码:600 / 642
页数:43
相关论文
共 259 条
[1]   Biomass pretreatment: Fundamentals toward application [J].
Agbor, Valery B. ;
Cicek, Nazim ;
Sparling, Richard ;
Berlin, Alex ;
Levin, David B. .
BIOTECHNOLOGY ADVANCES, 2011, 29 (06) :675-685
[2]   Rheological characterization of microfibrillated cellulose suspensions after freezing [J].
Agoda-Tandjawa, G. ;
Durand, S. ;
Berot, S. ;
Blassel, C. ;
Gaillard, C. ;
Garnier, C. ;
Doublier, J. -L. .
CARBOHYDRATE POLYMERS, 2010, 80 (03) :677-686
[3]  
Ahn S.-H, 2009, E-POLYMERS, V102, P1
[4]   Cellulose nanofibrils-adsorption with poly(amideamine) epichlorohydrin studied by QCM-D and application as a paper strength additive [J].
Ahola, Susanna ;
Osterberg, Monika ;
Laine, Janne .
CELLULOSE, 2008, 15 (02) :303-314
[5]   Buildup of polyelectrolyte multilayers of polyethyleneimine and microfibrillated cellulose studied by in situ dual-polarization interferometry and quartz crystal microbalance with dissipation [J].
Aulin, Christian ;
Varga, Imre ;
Claessont, Per M. ;
Wagberg, Lars ;
Lindstrom, Tom .
LANGMUIR, 2008, 24 (06) :2509-2518
[6]   Aerogels from nanofibrillated cellulose with tunable oleophobicity [J].
Aulin, Christian ;
Netrval, Julia ;
Wagberg, Lars ;
Lindstrom, Tom .
SOFT MATTER, 2010, 6 (14) :3298-3305
[7]   Oxygen and oil barrier properties of microfibrillated cellulose films and coatings [J].
Aulin, Christian ;
Gallstedt, Mikael ;
Lindstrom, Tom .
CELLULOSE, 2010, 17 (03) :559-574
[8]   Water sorption behavior and gas barrier properties of cellulose whiskers and microfibrils films [J].
Belbekhouche, Sabrina ;
Bras, Julien ;
Siqueira, Gilberto ;
Chappey, Corinne ;
Lebrun, Laurent ;
Khelifi, Bertine ;
Marais, Stephane ;
Dufresne, Alain .
CARBOHYDRATE POLYMERS, 2011, 83 (04) :1740-1748
[9]   Cellulosic nanoparticles from alfa fibers (Stipa tenacissima): extraction procedures and reinforcement potential in polymer nanocomposites [J].
Ben Mabrouk, Ayman ;
Kaddami, Hamid ;
Boufi, Sami ;
Erchiqui, Fouad ;
Dufresne, Alain .
CELLULOSE, 2012, 19 (03) :843-853
[10]   Investigation on the effect of cellulosic nanoparticles' morphology on the properties of natural rubber based nanocomposites [J].
Bendahou, Abdelkader ;
Kaddami, Hamid ;
Dufresne, Alain .
EUROPEAN POLYMER JOURNAL, 2010, 46 (04) :609-620