Structural, morphological and photoluminescence studies of multi shells coated ZnO nanocomposites

被引:8
作者
Ramasamy, V. [1 ]
Anandan, C. [1 ]
Murugadoss, G. [2 ]
机构
[1] Annamalai Univ, Dept Phys, Annamalainagar 608002, Tamil Nadu, India
[2] Anna Univ, Ctr Nanosci & Technol, Madras 600025, Tamil Nadu, India
关键词
Nanocomposite; Core-shell; Surface defects; Quantum confinement; PL; OPTICAL-PROPERTIES; QUANTUM DOTS; NANOPARTICLES; SIZE; NANOCRYSTALS; NANOWIRES; NANOSTRUCTURES; REDUCTION; DYNAMICS; POWDERS;
D O I
10.1016/j.spmi.2013.06.021
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
ZnO/CdS/ZnS (0.1-0.5 M) nanocomposites were successfully synthesized by chemical method and excellent optical properties were reported. Obtained samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), Photoluminescence (PL), UV-visible spectrophotometer and thermo gravimetric-differential thermal analysis (TG-DTA). The XRD results showed cubic structure of CdS and ZnS were (size of about >5 nm) grew on the surface of the hexagonal ZnO nanoparticles. The measurement of luminescence revealed that ZnO/CdS/ZnS core-shell integrated the luminescent effect of ZnO, CdS and ZnS. Broad blue and sharp yellow emissions were observed for ZnO/CdS/ZnS core-shell nanocomposites. In addition, thermal stability was also analyzed. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:106 / 114
页数:9
相关论文
共 32 条
[1]   Photoluminescence and Photoconductivity of ZnS-Coated ZnO Nanowires [J].
Bera, Ashok ;
Basak, Durga .
ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (02) :408-412
[2]   Effect of Surface Capping with Poly(vinyl alcohol) on the Photocarrier Relaxation of ZnO Nanowires [J].
Bera, Ashok ;
Basak, Durga .
ACS APPLIED MATERIALS & INTERFACES, 2009, 1 (09) :2066-2070
[3]   MATERIALS SCIENCE - NANOSTRUCTURES COME OF AGE [J].
CAHN, RW .
NATURE, 1992, 359 (6396) :591-592
[4]   Size dependence of structural metastability in semiconductor nanocrystals [J].
Chen, CC ;
Herhold, AB ;
Johnson, CS ;
Alivisatos, AP .
SCIENCE, 1997, 276 (5311) :398-401
[5]   (CdSe)ZnS core-shell quantum dots: Synthesis and characterization of a size series of highly luminescent nanocrystallites [J].
Dabbousi, BO ;
RodriguezViejo, J ;
Mikulec, FV ;
Heine, JR ;
Mattoussi, H ;
Ober, R ;
Jensen, KF ;
Bawendi, MG .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (46) :9463-9475
[6]   LUMINESCENT PROPERTIES OF ZNS-MN FILMS DEPOSITED BY SPRAY PYROLYSIS [J].
FALCONY, C ;
GARCIA, M ;
ORTIZ, A ;
ALONSO, JC .
JOURNAL OF APPLIED PHYSICS, 1992, 72 (04) :1525-1527
[7]   Zinc oxide nanostructures: Synthesis and properties [J].
Fan, ZY ;
Lu, JG .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2005, 5 (10) :1561-1573
[8]   Surface characteristics of ZnS nanocrystallites relating to their photocatalysis for CO2 reduction [J].
Fujiwara, H ;
Hosokawa, H ;
Murakoshi, K ;
Wada, Y ;
Yanagida, S .
LANGMUIR, 1998, 14 (18) :5154-5159
[9]   Sonochemical synthesis, optical properties, and electrical properties of core/shell-type ZnO nanorod/CdS nanoparticle composites [J].
Gao, T ;
Li, QH ;
Wang, TH .
CHEMISTRY OF MATERIALS, 2005, 17 (04) :887-892
[10]   Nanostructured materials: Basic concepts and microstructure [J].
Gleiter, H .
ACTA MATERIALIA, 2000, 48 (01) :1-29