Origin of similarity of phase diagrams in amphiphilic and colloidal systems with competing interactions

被引:95
作者
Ciach, A. [1 ]
Pekalski, J. [1 ]
Gozdz, W. T. [1 ]
机构
[1] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland
关键词
RANGE; CLUSTERS;
D O I
10.1039/c3sm50668a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We show that amphiphilic and colloidal systems with competing interactions can be described by the same Landau-Brazovskii functional. The functional is obtained by a systematic coarse-graining procedure applied to systems with isotropic interaction potentials. Microscopic expressions for the coefficients in the functional are derived. We propose simple criteria to distinguish the effective interparticle potentials that can lead to macro-or microsegregation. Our considerations also concern charged globular proteins in aqueous solutions and other systems with effective short-range attraction long-range repulsion interactions.
引用
收藏
页码:6301 / 6308
页数:8
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