Origin of similarity of phase diagrams in amphiphilic and colloidal systems with competing interactions

被引:95
作者
Ciach, A. [1 ]
Pekalski, J. [1 ]
Gozdz, W. T. [1 ]
机构
[1] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland
关键词
RANGE; CLUSTERS;
D O I
10.1039/c3sm50668a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We show that amphiphilic and colloidal systems with competing interactions can be described by the same Landau-Brazovskii functional. The functional is obtained by a systematic coarse-graining procedure applied to systems with isotropic interaction potentials. Microscopic expressions for the coefficients in the functional are derived. We propose simple criteria to distinguish the effective interparticle potentials that can lead to macro-or microsegregation. Our considerations also concern charged globular proteins in aqueous solutions and other systems with effective short-range attraction long-range repulsion interactions.
引用
收藏
页码:6301 / 6308
页数:8
相关论文
共 42 条
  • [1] MODULATED STRUCTURES AND COMPETING INTERACTIONS IN AMPHIPHILIC MONOLAYERS
    ANDELMAN, D
    BROCHARD, F
    JOANNY, JF
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1987, 84 (14) : 4717 - 4718
  • [2] Model colloidal fluid with competing interactions: Bulk and interfacial properties
    Archer, A. J.
    Pini, D.
    Evans, R.
    Reatto, L.
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2007, 126 (01)
  • [3] Archer A. J., 2012, PHYS REV E, V46
  • [4] Phase behavior of a fluid with competing attractive and repulsive interactions
    Archer, Andrew J.
    Wilding, Nigel B.
    [J]. PHYSICAL REVIEW E, 2007, 76 (03):
  • [5] Two-dimensional fluid with competing interactions exhibiting microphase separation: Theory for bulk and interfacial properties
    Archer, Andrew J.
    [J]. PHYSICAL REVIEW E, 2008, 78 (03):
  • [6] Barrat J.-L., 2003, Basic Concepts for Simple and Complex Liquids
  • [7] BRAZOVSKII SA, 1975, SOV PHYS JETP, V41, P8
  • [8] Dynamical arrest in attractive colloids: The effect of long-range repulsion
    Campbell, AI
    Anderson, VJ
    van Duijneveldt, JS
    Bartlett, P
    [J]. PHYSICAL REVIEW LETTERS, 2005, 94 (20)
  • [9] Phase behavior and far-from-equilibrium gelation in charged attractive colloids
    Charbonneau, P.
    Reichman, D. R.
    [J]. PHYSICAL REVIEW E, 2007, 75 (05):
  • [10] Ciach A, 2010, CONDENS MATTER PHYS, V13, DOI 10.5488/CMP.13.23603