In situ synchrotron X-ray diffraction studies of lithium oxygen batteries

被引：21

作者：

Ryan, Kate R. ^{[1
]}

Trahey, Lynn ^{[1
]}

Okasinski, John S. ^{[2
]}

Burrell, Anthony K. ^{[1
]}

Ingram, Brian J. ^{[1
]}

机构：

[1] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA

[2] Argonne Natl Lab, Adv Photon Source, Xray Sci Div, Argonne, IL 60439 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2013年 / 1卷 / 23期

关键词：

LI-O-2; BATTERIES; AIR BATTERIES; ETHER; SOLVENTS; STABILITY; EVOLUTION; BEHAVIOR; XRD;

D O I：

10.1039/c3ta10361g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Lithium oxygen batteries were studied in situ by synchrotron X-ray diffraction. Crystalline Li2O2 was shown to form reversibly on a plain carbon cathode under normal cycling conditions. However, if the cell was polarized to induce electrolyte decomposition before the oxygen reduction reaction was initiated, LiOH was found to cycle reversibly on the cathode instead. A mechanism linking the LiOH production to the electrolyte decomposition was proposed.

引用

页码：6915 / 6919

页数：5

共 50 条

[21] In-situ X-ray diffraction study on the structural evolutions of oxidized fluorophosphates as anode materials for lithium-ion batteries
Lin, Xiaoting
Ma, Rui
Shao, Lianyi
Shui, Miao
Wu, Kaiqiang
Wang, Dongjie
Long, Nengbing
Ren, Yuanlong
Shu, Jie
CERAMICS INTERNATIONAL, 2014, 40 (07) : 9107 - 9120
[22] High pressure synchrotron x-ray diffraction and Raman scattering studies of ammonium azide
Wu, Xiaoxin
Cui, Hang
Zhang, Jian
Cong, Ridong
Zhu, Hongyang
Cui, Qiliang
APPLIED PHYSICS LETTERS, 2013, 102 (12)
[23] High Pressure Raman Scattering and Synchrotron X-ray Diffraction Studies of Benzyl Azide
Jiang, Junru
Wu, Xiaoxin
Li, Dongmei
Ma, Boheng
Liu, Ruirui
Wang, Xiaoli
Zhang, Jian
Zhu, Hongyang
Cui, Qiliang
JOURNAL OF PHYSICAL CHEMISTRY B, 2015, 119 (02) : 513 - 518
[24] Structure studies on LiMn0.25Fe0.75PO4 by in-situ synchrotron X-ray diffraction analysis
Chen, Yi-Chun
Chen, Jin-Ming
Hsu, Chia-Haw
Yeh, Jien-Wei
Shih, Han C.
Chang, Yee-Shyi
Sheu, Hwo-Shuenn
JOURNAL OF POWER SOURCES, 2009, 189 (01) : 790 - 793
[25] Probing Titanium Disulfide-Sulfur Composite Materials for Li-S Batteries via In Situ X-ray Diffraction (XRD)
Zhang, Qing
Bock, David C.
Takeuchi, Kenneth J.
Marschilok, Amy C.
Takeuchi, Esther S.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2017, 164 (04) : A897 - A901
[26] An in situ synchrotron X-ray diffraction study of precipitation kinetics in a severely deformed Cu-Ni-Si alloy
Azzeddine, H.
Mehdi, B.
Hennet, L.
Thiaudiere, D.
Alili, B.
Kawasaki, M.
Bradai, D.
Langdon, T. G.
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2014, 597 : 288 - 294
[27] In-situ x-ray absorption fine structure and x-ray diffraction studies of hydrogen intercalation in tungsten oxides
Purans, J
Kuzmin, A
Guery, C
OPTICAL ORGANIC AND SEMICONDUCTOR INORGANIC MATERIALS, 1997, 2968 : 174 - 179
[28] In situ X-ray diffraction studies of hydrous aluminosilicate at high pressure and temperature
Abe, Ryota
Shibazaki, Yuki
Ozawa, Shin
Ohira, Itaru
Tobe, Hiromu
Suzuki, Akio
JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES, 2018, 113 (02) : 106 - 111
[29] Synchrotron X-ray diffraction studies of the internal load transfer in Ni-CrC metal matrix composites
Li, Jianxiong
Shanks, Katherine S.
Das, Amlan
Nault, Isaac M.
Hassani, Mostafa
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2024, 911
[30] Oxidation of Micro- and Nanograined UO2 Pellets by In Situ Synchrotron X-ray Diffraction
De Bona, Emanuele
Popa, Karin
Walter, Olaf
Cologna, Marco
Hennig, Christoph
Scheinost, Andreas C.
Prieur, Damien
INORGANIC CHEMISTRY, 2022, 61 (04) : 1843 - 1850

← 1 2 3 4 5 →