Phase diagram and thermodynamic properties of H2

被引：1
|
作者：
Osman, S. M. [1 ]
Ali, I. [1 ]
Singh, R. N. [1 ]
机构：
[1] Sultan Qaboos Univ, Dept Phys, Coll Sci, Al Khoud 123, Oman
来源：
PHYSICAL REVIEW E | 2013年 / 87卷 / 01期
关键词：
EQUATION-OF-STATE; SURFACE-TENSION; SOUND-VELOCITY; FLUID HYDROGEN; LIQUID; DENSITY; METALLIZATION; TEMPERATURE; EQUILIBRIUM; PARAMETERS;
D O I：
10.1103/PhysRevE.87.012122
中图分类号：
O35 [流体力学]; O53 [等离子体物理学];
学科分类号：
070204 ; 080103 ; 080704 ;
摘要：
A statistical mechanical-based theory is used to develop the equation of state for the molecular fluid of H-2. We incorporate in this equation the long-range correlations through the double Yukawa potential, dimerization of the H-2 molecule by treating the fluid as a hard convex body fluid, and first-order quantum correction which is important at low temperatures. We use this to calculate the liquid-vapor equilibrium of H-2, including the temperature and pressure dependence of compressibility factor, entropy, specific heat, compressibility, and sound velocity. DOI: 10.1103/PhysRevE.87.012122
引用
收藏
页数：7
相关论文
共 50 条
  • [1] Phase diagram of H2 adsorbed on graphene
    Gordillo, M. C.
    Boronat, J.
    PHYSICAL REVIEW B, 2010, 81 (15):
  • [2] Modeling of thermodynamic properties of H2 and H2 mixtures using a three cubic of state
    Sevestre, Clement
    Chabab, Salaheddine
    Brocus, Julien
    Coquelet, Christophe
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2025, 101 : 1029 - 1043
  • [3] Thermodynamic properties and phase diagram for the system MoO2-TiO2
    Jacob, K. Thomas
    Shekhar, Chander
    Waseday, Yoshio
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2008, 91 (02) : 563 - 568
  • [4] Properties and phase diagram of (H2S)2H2
    Pace, Edward J.
    Liu, Xiao-Di
    Dalladay-Simpson, Philip
    Binns, Jack
    Pena-Alvarez, Miriam
    Attfield, J. Paul
    Howie, Ross T.
    Gregoryanz, Eugene
    PHYSICAL REVIEW B, 2020, 101 (17)
  • [5] Phase diagram of CaSO4 reductive decomposition by H2 and CO
    Min Zheng
    Yanbing Xing
    Simei Zhong
    Hua Wang
    Korean Journal of Chemical Engineering, 2017, 34 : 1266 - 1272
  • [6] Phase diagram of CaSO4 reductive decomposition by H2 and CO
    Zheng, Min
    Xing, Yanbing
    Zhong, Simei
    Wang, Hua
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2017, 34 (04) : 1266 - 1272
  • [7] Phase Diagram and Thermodynamic Properties of the EuBr2-CsBr Binary System
    Rycerz, Leszek
    Kapala, Jan
    Gaune-Escard, Marcelle
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2021, 66 (05): : 1939 - 1946
  • [8] Estimation of Thermodynamic Properties from Binary Phase Diagram
    王纪鑫
    Journal of Materials Science & Technology, 1992, (01) : 44 - 50
  • [9] Studies on the thermodynamic and kinetic properties of reactions of BO(BS) with H2
    Yin, Ping
    Hu, Yucai
    Zheng, Hegen
    Du, Qingjun
    Liu, Bing
    Jiang, Wei
    PROGRESS IN REACTION KINETICS AND MECHANISM, 2006, 31 (01) : 1 - 9
  • [10] Phase diagram and thermodynamic properties of Ag−Cu alloys
    Youqing Xie
    Xiaodong Zhang
    Science in China Series E: Technological Sciences, 1998, 41 : 348 - 356
12345