Abnormal, mesoionic and remote N-heterocyclic carbene complexes

被引：493
|
作者：
Crabtree, Robert H. [1 ,2 ]
机构：
[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA
[2] Energy Sci Inst, New Haven, CT 06520 USA
来源：
COORDINATION CHEMISTRY REVIEWS | 2013年 / 257卷 / 3-4期
关键词：
NHC; MIC; Catalysis; NORBORNENE POLYMERIZATION BEHAVIOR; PALLADIUM COMPLEXES; IMIDAZOLIUM SALTS; ELECTRONIC PARAMETERS; IRIDIUM COMPLEXES; NHC LIGANDS; REACTIVITY; DONOR; ACTIVATION; PHOSPHINE;
D O I：
10.1016/j.ccr.2012.09.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three different structural classes of NHC ligands can be distinguished: normal (nNHC), abnormal (aNHC), alternatively called mesoionic (MIC), and remote (rNHC). General principles, synthetic strategies as well as recent results in the area of transition metal complexes of aNHC/MICs and rNHCs are discussed. The special properties of aNHC/MICs are discussed including their somewhat debateable status as true carbenes in the full sense of the term, as contrasted with their close analogy with nNHCs in the bound state. Some applications to catalysis are included and future prospects outlined. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：755 / 766
页数：12
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