Interconnected network of ultrafine MnO2 nanowires on carbon cloth with weed-like morphology for high-performance supercapacitor electrodes

被引:58
作者
Xu, Zhihui [1 ]
Sun, Shishuai [1 ]
Cui, Wen [2 ]
Lv, Jiang [1 ]
Geng, Yaohui [1 ]
Li, Hui [1 ]
Deng, Jiachun [1 ]
机构
[1] Tianjin Univ Technol, Coll Sci, Tianjin 300384, Peoples R China
[2] Tianjin Normal Univ, Coll Phys & Mat Sci, Tianjin 300387, Peoples R China
基金
中国国家自然科学基金;
关键词
MnO2; Supercapacitor; Electrode; Nanowire; Ultrafine structure; FACILE SYNTHESIS; MANGANESE OXIDE; NANORODS; DELTA-MNO2; NANOFIBERS; ARRAYS; SHEETS; FILM;
D O I
10.1016/j.electacta.2018.02.138
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A binder-free electrode of ultrafine MnO2 nanowires grown on the carbon cloth (CC) were fabricated by simple hydrothermal method, exhibiting the interconnected network with weed-like morphological feature. The unique pore structure has a large interface surface area, and allows rapid electrolyte diffusion through its hollow/open framework and fast electron transfer though the carbon skeleton. As an electrode for supercapacitors, the ultrafine MnO2 nanowires grown on the CC (ultrafine MnO2 nanowires@CC) exhibit a high specific capacitance (1174.3 F g(-1) at the moderate current density of 2 A g(-1)), excellent rate property (stabilize at 927 F g(-1) as the current density increases to 40 A g(-1)), and good cycling stability (a negligible 0.1% decay in specific capacitances after 10,000 cycles). (c) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码:340 / 346
页数:7
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