Synthesis of a smart Janus-like supramolecular polymer based on the host-guest chemistry and its self-assembly

被引：13
|
作者：
Yang, Long [1 ]
Guo, Yinzhou [1 ]
Lei, Zhongli [1 ]
机构：
[1] Shaanxi Normal Univ, Minist Educ, Key Lab Appl Surface & Colloid Chem, Xian 710062, Peoples R China
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2015年 / 3卷 / 33期
基金：
中国国家自然科学基金;
关键词：
BLOCK-COPOLYMERS; PARTICLES; COMPLEXES; VESICLES; MICELLES; SPHERES; WATER;
D O I：
10.1039/c5ta03937a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We report on the double stimuli-responsive self-assembly of a Janus-like supramolecular polymer based on the host-guest chemistry. It is constructed by the noncovalent coupling between a hyperbranched PMAA with an apex of an adamantane (Ad) group and a hyperbranched PNIPAAm with an apex of a beta-cyclodextrin (beta-CD) group. Upon adjusting the solution pH or temperature, the supramolecular polymer can reversibly self-assemble in solution.
引用
收藏
页码：17098 / 17105
页数：8
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