Low-cost process to utilize sodium salts for porous cellulose materials

被引:5
作者
Lee, Hwa Jin [1 ]
Cho, Younghyun [2 ]
Kang, Sang Wook [1 ,3 ]
机构
[1] Sangmyung Univ, Dept Chem, Seoul 03016, South Korea
[2] Soonchunhyang Univ, Dept Energy Syst Engn, Asan 31538, South Korea
[3] Sangmyung Univ, Dept Chem & Energy Engn, Seoul 03016, South Korea
基金
新加坡国家研究基金会;
关键词
Sodium salt; Porous; Plasticization; Porosity; Hydration; PORE-GENERATION; IONIC LIQUID; MEMBRANE; ACETATE; NITRATE;
D O I
10.1016/j.jiec.2022.06.011
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The porous cellulose materials are fabricated from cellulose acetate (CA) and Na salts. When composite films consisting of CA and NaNO3 are exposed to water-pressure, the maximum flux reached to 8.6 L.mz.h(-1). The generated water flux is attributable to the partial plasticization in polymer chains by hydrated NaNO3. The flexible polymer chains by hydrated salts can be the pores by external physical forces. Surprisingly, the CA/NaNO3 film shows a high porosity of 78.15 % and pore shapes was confirmed via scanning electron microscopy. Moreover, it preserves the excellent heat resistance properties, confirmed by thermal gravimetric analysis. (C) 2022 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:368 / 372
页数:5
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