An octahedrally coordinated trialkylyttrium(III): tris(trimethylsilylmethyl)(1,4,7-trimethyl-1,4,7-triazacyclononane)yttrium(III)

被引:14
|
作者
Bambirra, S [1 ]
Meetsma, A [1 ]
Hessen, B [1 ]
机构
[1] Univ Groningen, Dept Organ & Mol Inorgan Chem, Groningen Ctr Catalysis & Synth, NL-9747 AG Groningen, Netherlands
关键词
D O I
10.1107/S1600536806001450
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The crystal structure of the title compound, [Y(C4H11Si) 3( C9H21N3)], consists of monomeric species. In each of the three independent molecules in the asymmetric unit, the Y atom is in a slightly distorted octahedral environment, formed by the C atoms of three trimethylsilylmethyl ligands ( average Y - C = 2.427 angstrom) and three facially bound N atoms of the 1,4,7-trimethyl-1,4,7-triazacyclonane ligand ( average Y - N = 2.601 angstrom).
引用
收藏
页码:M314 / M316
页数:3
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