Graphene oxides-guided growth of ultrafine Co3O4 nanocrystallites from MOFs as high-performance anode of Li-ion batteries

被引：87
作者：
Qu, Qunting [1 ,2 ]
Gao, Tian [1 ,2 ]
Zheng, Huiyuan [1 ,2 ]
Li, Xingxing [1 ,2 ]
Liu, Hongmei [1 ,2 ]
Shen, Ming [3 ]
Shao, Jie [4 ]
Zheng, Honghe [1 ,2 ]
机构：
[1] Soochow Univ, Coll Phys Optoelect & Energy, Suzhou 215006, Jiangsu, Peoples R China
[2] Soochow Univ, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, Suzhou 215006, Jiangsu, Peoples R China
[3] Huasheng Chem Corp, Zhangjiagang 215635, Jiangsu, Peoples R China
[4] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215006, Jiangsu, Peoples R China
来源：
CARBON | 2015年 / 92卷
基金：
中国国家自然科学基金;
关键词：
ENHANCED ELECTROCHEMICAL PERFORMANCE; METAL-ORGANIC FRAMEWORKS; NEGATIVE ELECTRODES; LITHIUM; STORAGE; CAPACITY; COMPOSITE; NANOPARTICLES; ARCHITECTURES; MICROSPHERES;
D O I：
10.1016/j.carbon.2015.03.061
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This work presents the self-assembly growth of metal organic frameworks (ZIF-67) dodecahedrons on graphene oxides (GO) nanosheets. Ultrafine Co3O4 nanocrystallites with size of less than 10 nm are uniformly spread on graphene nanosheets through pyrolysis of GO/ZIF-67. The relative mass ratio of graphene to Co3O4 is controlled by adjusting the repeated numbers of GO in precursor solutions. For application as anode material of Li-ion batteries, graphene/Co3O4 manifests good high rate behavior (877 mAh g(-1) at the current density of 5000 mA g(-1)) and long-term cycling stability (714 mAh g(-1) after 200 cycles). (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：119 / 125
页数：7
相关论文
共 50 条
  • [1] MOFs-derived Co3O4/MWCNTs composite as high-performance anode materials for Li-ion batteries
    Guan, Ruohan
    Dong, Guixia
    Li, Zongfeng
    Yang, Shuangjuan
    MATERIALS LETTERS, 2022, 307
  • [2] Construction of hollow Co3O4 cubes as a high-performance anode for lithium ion batteries
    Li, Li
    Zhang, Zichao
    Ren, Sijia
    Zhang, Bingke
    Yang, Shuhua
    Cao, Bingqiang
    NEW JOURNAL OF CHEMISTRY, 2017, 41 (16) : 7960 - 7965
  • [3] Co3O4 and its composites for high-performance Li-ion batteries
    Shi, Yuxin
    Pan, Xiaofan
    Li, Bing
    Zhao, Mingming
    Pang, Huan
    CHEMICAL ENGINEERING JOURNAL, 2018, 343 : 427 - 446
  • [4] MOF-derived porous hollow Co3O4 parallelepipeds for building high-performance Li-ion batteries
    Han, Yan
    Zhao, Mengli
    Dong, Lei
    Feng, Jianmin
    Wang, Yijing
    Li, Dejun
    Li, Xifei
    JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (45) : 22542 - 22546
  • [5] Double modification to effectively improve electrochemical performance of Co3O4 as Li-ion batteries anode
    Zhang, KaiBo
    Guo, PeiYi
    Zeng, Min
    Zhang, YuQing
    Bai, Yuan
    Li, Jing
    MATERIALS LETTERS, 2020, 280
  • [6] A 3D porous architecture of Si/graphene nanocomposite as high-performance anode materials for Li-ion batteries
    Xin, Xing
    Zhou, Xufeng
    Wang, Feng
    Yao, Xiayin
    Xu, Xiaoxiong
    Zhu, Yimei
    Liu, Zhaoping
    JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (16) : 7724 - 7730
  • [7] Hierarchically ordered mesoporous Co3O4 materials for high performance Li-ion batteries
    Sun, Shijiao
    Zhao, Xiangyu
    Yang, Meng
    Wu, Linlin
    Wen, Zhaoyin
    Shen, Xiaodong
    SCIENTIFIC REPORTS, 2016, 6
  • [8] Synthesis and characterization of Co3O4 nanoparticles: Application as performing anode in Li-ion batteries
    Mahmood, Zaid Hameed
    Jarosova, Marketa
    Kzar, Hamzah H.
    Machek, Pavel
    Zaidi, Muhaned
    Khalaji, Aliakbar Dehno
    Khlewee, Ibrahim Hammoud
    Altimari, Usama S.
    Mustafa, Yasser Fakri
    Kadhim, Mustafa M.
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2022, 69 (04) : 657 - 662
  • [9] In situ growth of mesoporous Co3O4 nanoparticles on graphene as a high-performance anode material for lithium-ion batteries
    Qiu, Danfeng
    Bu, Gang
    Zhao, Bin
    Lin, Zixia
    Pu, Lin
    Pan, Lijia
    Shi, Yi
    MATERIALS LETTERS, 2014, 119 : 12 - 15
  • [10] Co3O4/porous electrospun carbon nanofibers as anodes for high performance Li-ion batteries
    Abouali, Sara
    Garakani, Mohammad Akbari
    Zhang, Biao
    Luo, Hui
    Xu, Zheng-Long
    Huang, Jian-Qiu
    Huang, Jiaqiang
    Kim, Jang-Kyo
    JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (40) : 16939 - 16944
12345