α,β-Unsaturated imines via Ru-catalyzed coupling of allylic alcohols and amines

被引：60

作者：

Rigoli, Jared W. ^{[1
]}

Moyer, Sara A. ^{[1
]}

Pearce, Simon D. ^{[1
]}

Schomaker, Jennifer M. ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2012年 / 10卷 / 09期

关键词：

TRANSITION-METAL COMPLEXES; DIRECT AMIDE SYNTHESIS; RUTHENIUM COMPLEXES; N-ALKYLATION; ISOMERIZATION; ACTIVATION; OXIDATION; CYCLOADDITION; SULFONAMIDES; LIBERATION;

D O I：

10.1039/c2ob06921k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A convenient synthesis of alpha,beta-unsaturated imines requiring only an allylic alcohol, an amine and a Ru catalyst has been developed. The use of large excesses of oxidant and the purification of sensitive intermediates can be avoided.

引用

页码：1746 / 1749

页数：4

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