α,β-Unsaturated imines via Ru-catalyzed coupling of allylic alcohols and amines

被引：60
|
作者：
Rigoli, Jared W. [1 ]
Moyer, Sara A. [1 ]
Pearce, Simon D. [1 ]
Schomaker, Jennifer M. [1 ]
机构：
[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2012年 / 10卷 / 09期
关键词：
TRANSITION-METAL COMPLEXES; DIRECT AMIDE SYNTHESIS; RUTHENIUM COMPLEXES; N-ALKYLATION; ISOMERIZATION; ACTIVATION; OXIDATION; CYCLOADDITION; SULFONAMIDES; LIBERATION;
D O I：
10.1039/c2ob06921k
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A convenient synthesis of alpha,beta-unsaturated imines requiring only an allylic alcohol, an amine and a Ru catalyst has been developed. The use of large excesses of oxidant and the purification of sensitive intermediates can be avoided.
引用
收藏
页码：1746 / 1749
页数：4
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