Two 3D coordination polymers constructed from flexible desymmetric carboxylate and neutral nitrogen ligands

被引：7
作者：
Ping, Yun-Jie [1 ]
Yan, Ru-Yong [1 ]
Zhao, Gao-Chao [1 ]
Qin, Ling [1 ]
Zheng, He-Gen [2 ]
机构：
[1] Hefei Univ Technol, Dept Chem Engn & Food Proc, Xuancheng 242000, Anhui, Peoples R China
[2] Nanjing Univ, Sch Chem & Chem Engn, Innovat Ctr Adv Microstruct, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 61卷
基金：
中国国家自然科学基金;
关键词：
Desymmetric ligand; Second harmonic generation; Coordination polymer; METAL-ORGANIC FRAMEWORKS; ADSORPTION; BEHAVIORS; LINKER;
D O I：
10.1016/j.inoche.2015.09.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two coordination polymers based on a flexible desymmetric ligand precursor H2L have been synthesized, that is, [Ni(L)(dpe)(3/2)]center dot H2O (1), [Ni-2(H2O)(L)(2)(bPP)(2)]center dot H2O (2), [H2L = 4,4'-(phenylazanediypdibenzoic acid, dpe = 1,2-di(pyridin-4-yl)ethane, bpp = 1,3-di(pyridin-4-yl)propane]. These complexes were characterized by elemental analysis, IR spectroscopy, X-ray single-crystal and power diffraction. In addition, the second nonlinear optical-properties of 2 were measured. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：136 / 139
页数：4
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