Two new coordination polymers based on hexanuclear metal cluster cores

被引：35

作者：

Chen, Jinxi ^{[1
]}

Ohba, Masaaki ^{[1
]}

Kitagawa, Susumu ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

CHEMISTRY LETTERS | 2006年 / 35卷 / 05期

关键词：

D O I：

10.1246/cl.2006.526

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new coordination polymers based on hexanuclear metal cluster cores, Zn-6(HCOO)(6)(DBrTPA)(3)(DMF)(6) (1) and Mn-6(HCOO)(6)(BTC)(2)(DMF)(6) (2) have been solvothermally synthesized. It is noteworthy that the formic ligands were in situ generated by the hydrolysis of DMF solvent under the solvothermal conditions and incorporated into these two compounds. The temperature-dependence of magnetic susceptibility for 2 shows antiferromagnetic interactions between metal centers.

引用

页码：526 / 527

页数：2

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