Femtosecond laser induced porosity in poly-methyl methacrylate

被引:27
作者
Baset, Farhana [1 ]
Villafranca, Ana [1 ]
Guay, Jean-Michel [1 ]
Bhardwaj, Ravi [1 ]
机构
[1] Univ Ottawa, Dept Phys, Ottawa, ON K1N 6N5, Canada
关键词
Laser material processing; Surface structuring; Femtosecond phenomena; Nanostructure fabrication; PERIODIC SURFACE-STRUCTURE; ABLATION; PULSES; PMMA; POLYCARBONATE; DIELECTRICS; IMPLANTS;
D O I
10.1016/j.apsusc.2013.06.043
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We show that femtosecond laser ablation of poly-methyl methacrylate (PMMA) induces porosity within the ablation crater that increases with pulse energy/fluence and number of laser shots. For deeper craters the porosity evolves into 3D honeycomb like structure on the sidewalls. Using imaging technique, we show that the porous area fraction decreases with pulse energy while the pore size distribution peaks at a pore area of 0.037 mu m(2) at higher energies. In line ablation, the pore size increases with the speed at which the laser focus is moved. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:729 / 734
页数:6
相关论文
共 36 条
  • [1] Pulsed laser evaporation: equation-of-state effects
    Anisimov, SI
    Inogamov, NA
    Oparin, AM
    Rethfeld, B
    Yabe, T
    Ogawa, M
    Fortov, VE
    [J]. APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1999, 69 (06): : 617 - 620
  • [2] Femtosecond laser induced surface swelling in poly-methyl methacrylate
    Baset, Farhana
    Popov, Konstantin
    Villafranca, Ana
    Guay, Jean-Michel
    Al-Rekabi, Zeinab
    Pelling, Andrew E.
    Ramunno, Lora
    Bhardwaj, Ravi
    [J]. OPTICS EXPRESS, 2013, 21 (10): : 12527 - 12538
  • [3] Ultrashort pulse laser ablation of polycarbonate and polymethylmethacrylate
    Baudach, S
    Bonse, J
    Krüger, J
    Kautek, W
    [J]. APPLIED SURFACE SCIENCE, 2000, 154 : 555 - 560
  • [4] Surface modifications induced by ns and sub-ps excimer laser pulses on titanium implant material
    Bereznai, M
    Pelsöczi, I
    Tóth, Z
    Turzó, K
    Radnai, M
    Bor, Z
    Fazekas, A
    [J]. BIOMATERIALS, 2003, 24 (23) : 4197 - 4203
  • [5] Optically produced arrays of planar nanostructures inside fused silica
    Bhardwaj, VR
    Simova, E
    Rajeev, PP
    Hnatovsky, C
    Taylor, RS
    Rayner, DM
    Corkum, PB
    [J]. PHYSICAL REVIEW LETTERS, 2006, 96 (05)
  • [6] Subwavelength ripple formation on the surfaces of compound semiconductors irradiated with femtosecond laser pulses
    Borowiec, A
    Haugen, HK
    [J]. APPLIED PHYSICS LETTERS, 2003, 82 (25) : 4462 - 4464
  • [7] Brunette D.M., 2001, TITANIUM MED MAT SCI
  • [8] Surface patterning on insulators upon femtosecond laser ablation
    Costache, F
    Henyk, M
    Reif, J
    [J]. APPLIED SURFACE SCIENCE, 2003, 208 : 486 - 491
  • [9] Surface Properties of Femtosecond Laser Ablated PMMA
    De Marco, Carmela
    Eaton, Shane M.
    Suriano, Raffaella
    Turri, Stefano
    Levi, Marinella
    Ramponi, Roberta
    Cerullo, Giulio
    Osellame, Roberto
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (08) : 2377 - 2384
  • [10] One-dimensional topography underlies three-dimensional fibrillar cell migration
    Doyle, Andrew D.
    Wang, Francis W.
    Matsumoto, Kazue
    Yamada, Kenneth M.
    [J]. JOURNAL OF CELL BIOLOGY, 2009, 184 (04) : 481 - 490