Bis(tetrasulfato)palladate, [Pd(S4O13)2]2-

被引：16

作者：

Bruns, Joern ^{[1
]}

Kluener, Thorsten ^{[1
]}

Wickleder, Mathias S. ^{[1
]}

机构：

[1] Carl von Ossietzky Univ Oldenburg, Inst Reine & Angew Chem, D-26129 Oldenburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 09期

关键词：

density functional calculations; palladium; polysulfates; structure elucidation; vibrational spectroscopy; CRYSTAL-STRUCTURE; UNIQUE; M=SI; GE; REFINEMENTS; ANION; SN;

D O I：

10.1002/anie.201209346

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

SOS: The first coordination compound containing polysulfate ligands was obtained under harsh conditions from the reaction of K2[PdCl 4] and SO3. The compound contains a Pd2+ ion coordinated by two chelating tetrasulfate anions (see structure, Pd red, S yellow, O blue), which leads to a significant stabilization of the polysulfate anions compared to their uncoordinated analogues. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2590 / 2592

页数：3