Alumina particles incorporated glass matrix composites, which showed good prospect to be used as coating materials for high-temperature corrosion protection on intermetallics or titanium alloys, were prepared via pressureless sintering. With increasing alumina content, the Young's modulus, fracture strength, Vickers hardness, indentation toughness, softening point, and thermal shock resistance of the composites increased monotonically. A similar increasing trend could be found for the thermal expansion coefficient of the composites, except for an abnormal drop at small amount of incorporation, which closely correlated with the Al3+ dissolution into the glass matrix.