Dynamic effect on the structure of X-ray photoelectron spectra of lanthanide fluorides and oxides

被引：1

作者：

Teterin, YA ^{[1
]}

Teterin, AY ^{[1
]}

Lebedev, AM ^{[1
]}

Utkin, IO ^{[1
]}

Nikitin, AS ^{[1
]}

机构：

[1] IV Kurchatov Atom Energy Inst, Russian Sci Ctr, Moscow 123182, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 1998年 / 39卷 / 06期

关键词：

D O I：

10.1007/BF02903596

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dynamic effect on the fine structure of X-ray photoelectron spectra of lanthanide oxides and fluorides is discussed. The Ln4p electron spectra are considerably complicated by the interaction between the configurations of the main one-hole and additional two-hole final states of 4p (5)4d (10)4f(n) <-> 4p (6)4d (8)4f(n+1) type. The effect of the nature of atoms in the nearest environment of lanthanide ions on the fine structure parameters is evaluated.

引用

页码：869 / 875

页数：7

共 20 条

[1] PREDICTION OF NEW MULTIPLET STRUCTURE IN PHOTOEMISSION EXPERIMENTS
BAGUS, PS
FREEMAN, AJ
SASAKI, F
[J]. PHYSICAL REVIEW LETTERS, 1973, 30 (18) : 850 - 853
[2] BAGUS PS, 1973, INT J QUANTUM CHEM, P83
[3] DEMEKHIN VF, 1979, ZH STRUKT KHIM, V20, P38
[4] KOWALCZYK SP, 1975, FARADAY DISCUSS, P7
[5] Larkins F. P., 1977, Atomic Data and Nuclear Data Tables, V20, P311, DOI 10.1016/0092-640X(77)90024-9
[6] MANY-ELECTRON EFFECTS IN L-GAMMA-2,3 X-RAY-EMISSION SPECTROSCOPY OF RARE-EARTH ELEMENTS
OHNO, M
LAVILLA, RE
[J]. PHYSICAL REVIEW B, 1989, 39 (13): : 8852 - 8857
[7] X-RAY PHOTOELECTRON CORE-LEVEL STUDIES OF HEAVY RARE-EARTH-METALS AND THEIR OXIDES
PADALIA, BD
LANG, WC
NORRIS, PR
WATSON, LM
FABIAN, DJ
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 1977, 354 (1678): : 269 - 290
[8] HARTREE-SLATER SUBSHELL PHOTOIONIZATION CROSS-SECTIONS AT 1254 AND 1487EV
SCOFIELD, JH
[J]. JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1976, 8 (02) : 129 - 137
[9] SIEGBAHN K, 1967, ESCA ATOMIC MOL SO 4, V20
[10] CONFIGURATION MIXING IN THE S-HOLE STATES OF METAL-IONS
SINGH, UC
SARMA, DD
RAO, CNR
[J]. CHEMICAL PHYSICS LETTERS, 1982, 85 (03) : 278 - 282

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