Amorphous Titanium Sulfide Electrode for All-solid-state Rechargeable Lithium Batteries with High Capacity

被引：56

作者：

Hayashi, Akitoshi ^{[1
]}

Matsuyama, Takuya ^{[1
]}

Sakuda, Atsushi ^{[1
]}

Tatsumisago, Masahiro ^{[1
]}

机构：

[1] Osaka Prefecture Univ, Dept Appl Chem, Naka Ku, Sakai, Osaka 5998531, Japan

来源：

CHEMISTRY LETTERS | 2012年 / 41卷 / 09期

基金：

日本科学技术振兴机构;

关键词：

CATHODES; SULFUR; GLASS;

D O I：

10.1246/cl.2012.886

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Amorphous TiS3 active materials were prepared using a high-energy ball mill and first applied to all-solid-state cells with Li2S-P2S5 solid electrolyte. The solid-state cell operated as a rechargeable lithium battery with a high capacity of 400 mA h g(-1) at room temperature. The cell exhibited a higher capacity than a solid-electrolyte cell with crystalline TiS2 and showed better cyclability than a liquid-electrolyte cell with crystalline TiS3.

引用

收藏

页码：886 / 888

页数：3

相关论文

共 13 条

[1] LATTICE PROPERTIES OF THE LINEAR-CHAIN COMPOUND TIS3 [J].

GALLIARDT, DW ;

NIEVEEN, WR ;

KIRBY, RD .

SOLID STATE COMMUNICATIONS, 1980, 34 (01) :37-39

[2] Formation of superionic crystals from mechanically milled Li2S-P2S5 glasses [J].

Hayashi, A ;

Hama, S ;

Minami, T ;

Tatsumisago, M .

ELECTROCHEMISTRY COMMUNICATIONS, 2003, 5 (02) :111-114

[3] TRANSITION-METAL SULFIDES AS CATHODES FOR SECONDARY LITHIUM BATTERIES .2. TITANIUM SULFIDES [J].

HOLLECK, GL ;

DRISCOLL, JR .

ELECTROCHIMICA ACTA, 1977, 22 (06) :647-655

[4] RECHARGEABLE SOLID-STATE BATTERY WITH LITHIUM CONDUCTIVE GLASS, LI3PO4-LI2S-SIS2 [J].

IWAMOTO, K ;

AOTANI, N ;

TAKADA, K ;

KONDO, S .

SOLID STATE IONICS, 1994, 70 :658-661

[5] Advances in Li-S batteries [J].

Ji, Xiulei ;

Nazar, Linda F. .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (44) :9821-9826

[6] Lithium intercalated compounds - Charge transfer and related properties [J].

Julien, CM .

MATERIALS SCIENCE & ENGINEERING R-REPORTS, 2003, 40 (02) :47-102

[7] XPS investigations of TiOySz amorphous thin films used as positive electrode in lithium microbatteries [J].

Lindic, MH ;

Martinez, H ;

Benayad, A ;

Pecquenard, B ;

Vinatier, P ;

Levasseur, A ;

Gonbeau, D .

SOLID STATE IONICS, 2005, 176 (17-18) :1529-1537

[8] Electrochemical properties of sulfur as cathode materials in a solid-state lithium battery with inorganic solid electrolytes [J].

Machida, N ;

Kobayashi, K ;

Nishikawa, Y ;

Shigematsu, T .

SOLID STATE IONICS, 2004, 175 (1-4) :247-250

[9] BEHAVIOR OF RAPIDLY QUENCHED V2O5 GLASS AT CATHODE IN LITHIUM CELLS [J].

MACHIDA, N ;

FUCHIDA, R ;

MINAMI, T .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (08) :2133-2136

[10] Sulfur-carbon composite electrode for all-solid-state Li/S battery with Li2S-P2S5 solid electrolyte [J].

Nagao, Motohiro ;

Hayashi, Akitoshi ;

Tatsumisago, Masahiro .

ELECTROCHIMICA ACTA, 2011, 56 (17) :6055-6059