Syntheses and Structures of Terpyridine-Metal Complexes

被引：17

作者：

Zhang, Na ^{[1
]}

Yang, Juan ^{[1
]}

Hu, Rui-Xiang ^{[1
]}

Zhang, Man-Bo ^{[1
]}

机构：

[1] Hunan Normal Univ, Key Lab Chem Biol & Tradit Chinese Med Res, Minist Educ, Coll Chem & Chem Engn, Changsha 410081, Hunan, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2013年 / 639卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Terpyridine; Transition metals; Lanthanides; Hydrothermal synthesis; HETEROMETALLIC COORDINATION POLYMERS; PHOTOPHYSICAL PROPERTIES; LANTHANIDE CLUSTERS; LAYERED NETWORKS; MIXED-LIGANDS; FRAMEWORKS; CRYSTAL; LUMINESCENCE; SORPTION; CONSTRUCTION;

D O I：

10.1002/zaac.201200339

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Seven complexes, [Ln(ctpy)(NO3)2]n and M(ctpy)2 center dot 4H2O [Ln = Gd (1), Dy (2), Er (3); M = Co (4), Ni (5), Cu (6), Zn (7)] with the ligand 2, 2':6',2 ''-terpyridine-4'-carboxylic acid (Hctpy) were hydrothermally synthesized. X-ray diffractional analysis reveals that the isomorphous compounds 13 adopt one-dimensional chain-like structures, whereas 47 are isomorphic monomers. Luminescence spectroscopy measurements indicates that compound 7 exhibits photoluminescence in the solid state at room temperature.

引用

页码：197 / 202

页数：6

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