Crystal structure modeling, electrical and thermal characterization of triple molybdates RbCrTi0.5(MoO4)3 (R=Fe, Cr)

被引：16

作者：

Dorzhieva, Sesegma G. ^{[1
]}

Bazarov, Bair G. ^{[1
]}

Subanakov, Alexey K. ^{[1
]}

Bazarova, Jibzema G. ^{[1
]}

机构：

[1] Baikal Inst Nat Management SB RAS, Ulan Ude 670047, Russia

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2013年 / 199卷

基金：

俄罗斯基础研究基金会;

关键词：

Molybdates; Rietveld refinement; Dielectric properties; Ionic; Conductivity; CONDUCTION; MOTION;

D O I：

10.1016/j.jssc.2012.11.023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new triple molybdates of RbRTi0.5(MoO4)(3) (R=Fe, Cr) were synthesized by a ceramic route at 580-600 degrees C. Their crystal structures have been refined by Rietveld analysis of powder X-ray diffraction data on the single crystal data of isostructural CsFeZr0.5(MoO4)(3) (trigonal symmetry, space group R-3). The structure refinement converged to satisfactory values of the Rietveld parameters, Rp and Rwp, and goodness of fit. The lattice parameters, bond lengths and bond angles have been calculated from Full Proff program. The maximum value of RbCrTi0.5(MoO4)(3) conductivity was 0.57 x 10(-2) S cm(-1) at 507 degrees C. Crown Copyright (C) 2012 Published by Elsevier Inc. All rights reserved.

引用

页码：21 / 26

页数：6

共 20 条

[1] Subsolidus phase diagrams of the systems Cs2MoO4-R2(MoO4)3-Zr(MoO4)2, where r = al, sc, or in [J].

Bazarov, B. G. ;

Namsaraeva, T. V. ;

Fedorov, K. N. ;

Bazarova, Zh. G. .

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2007, 52 (09) :1454-1458

[2]

Bazarov B. G., 2010, Doklady Akademii Nauk, V431, P58

[3]

Bazarov B.G., 2008, ZH STRUKT KHIM, V49, P58

[4]

Bazarov B.G., 2008, ZH NEORG KHIM, V53, P1585

[5]

GRINS J, 1983, SOLID STATE IONICS, V9-10, P85

[6] Lithium ion conduction in scheelite-type oxides and analysis of lithium ion motion by neutron radiography [J].

Hayashi, M ;

Sakaguchi, H ;

Takai, S ;

Esaka, T .

SOLID STATE IONICS, 2001, 140 (1-2) :71-76

[7] Potassium magnesium and potassium cobalt molybdates: Synthesis and ion conductivity [J].

Il'ina, A. A. ;

Stenina, I. A. ;

Veresov, A. G. ;

Yaroslavtsev, A. B. .

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2007, 52 (04) :469-474

[8] Trivalent ion conducting solid electrolytes [J].

Imanaka, N ;

Kobayashi, Y ;

Tamura, S ;

Adachi, G .

SOLID STATE IONICS, 2000, 136 (136-137) :319-324

[9]

KLEVTSOVA RF, 1995, ZH STRUKT KHIM, V0036

[10]

Mokhosoev M.V., 1981, DOUBLE MOLYBDATES TU

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