Evaluation of a canister method for the determination of volatile organic compounds by GC MS

被引：0

作者：

Imamura, K ^{[1
]}

Eguchi, M ^{[1
]}

Ohira, S ^{[1
]}

Tashiro, T ^{[1
]}

Tachibana, S ^{[1
]}

Tanaka, M ^{[1
]}

Hirai, K ^{[1
]}

Fujikata, Y ^{[1
]}

Fujise, G ^{[1
]}

Maeda, Y ^{[1
]}

Yasaka, Y ^{[1
]}

Warashina, M ^{[1
]}

机构：

[1] Assoc Environm Anal Osaka, Sect 23rd Cooperat Test, Nishi Ku, Osaka 5500004, Japan

来源：

BUNSEKI KAGAKU | 1999年 / 48卷 / 07期

关键词：

round-robin test; canister method; volatile organic hazardous air pollutants; gas chromatography mass spectrometry;

D O I：

暂无

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Round-robin tests were conducted in order to investigate a canister method for determining standard gas mixtures of volatile organic hazardous air pollutants by 14 members of the Association for Environmental Analysis in Osaka. A first standard gas containing seven analytes (acrylonitrile, dichloromethane, chloroform, 1,2-dichloroethane, benzene, trichloroethylene, and tetrachloroethylene at ca. 300 ppm each) was prepared in a glass vessel from their mixed solution according to our previous paper. An aliquot of this gas was transferred into a canister (61) using a syringe, and diluted (ca. 10 ppb each). The resulting standard gas mixture was evaluated by GC/MS after concentration. The obtained results prove this method to be both accurate and precise for the preparation of a standard gas mixture at low ppb levels. Another gas mixture containing nine analytes (vinyl chloride and 1,3-butadiene in addition to the above-mentioned seven compounds at 3 ppb each) was also prepared in a canister, and similarly treated by GC/MS. It was found that the canister method is remarkably accurate and precise. However, the acrylonitrile values had in large standard deviations.

引用

页码：717 / 723

页数：7