Synthesis of noble metal/graphene nanocomposites without surfactants by one-step reduction of metal salt and graphene oxide

被引:50
作者
Kim, Seung-Hyun [1 ]
Jeong, Gyoung Hwa [1 ,2 ]
Choi, Donghyeuk [1 ]
Yoon, Sunyoung [3 ]
Jeon, Heung Bae [3 ]
Lee, Sang-Min
Kim, Sang-Wook [1 ,2 ]
机构
[1] Ajou Univ, Dept Mol Sci & Technol, Suwon 443749, South Korea
[2] Ajou Univ, Ctr Mol Sci & Technol, Suwon 443749, South Korea
[3] Kwangwoon Univ, Dept Chem, Seoul 139701, South Korea
基金
新加坡国家研究基金会;
关键词
Graphene; Noble metal nanoparticle; Composite; Ascorbic acid; VITAMIN-C;
D O I
10.1016/j.jcis.2012.08.064
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We carried out hydrazine-free, surfactant-free synthesis of noble metal/graphene nanocomposites. The reduction of the noble metals and GO was carried out simultaneously in hot water using ascorbic acid as a reductant. In the noble metal/graphene nanocomposites of Pd, Pt, Au, and Ag nanoparticles, the GO and metal salts were reduced completely by this synthetic method. In addition, the Pd/graphene nanocomposites showed good catalytic activity in the Suzuki coupling reaction and could be reused many times without loss of catalytic activity. (C) 2012 Elsevier Inc. All rights reserved.
引用
收藏
页码:85 / 90
页数:6
相关论文
共 23 条
[1]   Functional Composite Materials Based on Chemically Converted Graphene [J].
Bai, Hua ;
Li, Chun ;
Shi, Gaoquan .
ADVANCED MATERIALS, 2011, 23 (09) :1089-1115
[2]   Synthesis of "Clean" and Well-Dispersive Pd Nanoparticles with Excellent Electrocatalytic Property on Graphene Oxide [J].
Chen, Xiaomei ;
Wu, Genghuang ;
Chen, Jinmei ;
Chen, Xi ;
Xie, Zhaoxiong ;
Wang, Xiaoru .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (11) :3693-3695
[3]   Lossless synthesis of graphene nanosheets decorated with tiny cadmium sulfide quantum dots with excellent nonlinear optical properties [J].
Feng, Miao ;
Sun, Ruiqing ;
Zhan, Hongbing ;
Chen, Yu .
NANOTECHNOLOGY, 2010, 21 (07)
[4]   Vitamin C Is an Ideal Substitute for Hydrazine in the Reduction of Graphene Oxide Suspensions [J].
Fernandez-Merino, M. J. ;
Guardia, L. ;
Paredes, J. I. ;
Villar-Rodil, S. ;
Solis-Fernandez, P. ;
Martinez-Alonso, A. ;
Tascon, J. M. D. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (14) :6426-6432
[5]   Environment-Friendly Method To Produce Graphene That Employs Vitamin C and Amino Acid [J].
Gao, Jian ;
Liu, Fang ;
Liu, Yiliu ;
Ma, Ning ;
Wang, Zhiqiang ;
Zhang, Xi .
CHEMISTRY OF MATERIALS, 2010, 22 (07) :2213-2218
[6]   Reduced graphene oxide as a catalyst for hydrogenation of nitrobenzene at room temperature [J].
Gao, Yongjun ;
Ma, Ding ;
Wang, Chunlei ;
Guan, Jing ;
Bao, Xinhe .
CHEMICAL COMMUNICATIONS, 2011, 47 (08) :2432-2434
[7]   Surface Modification of Graphene Nanosheets with Gold Nanoparticles: The Role of Oxygen Moieties at Graphene Surface on Gold Nucleation and Growth [J].
Goncalves, Gil ;
Marques, Paula A. A. P. ;
Granadeiro, Carlos M. ;
Nogueira, Helena I. S. ;
Singh, M. K. ;
Gracio, J. .
CHEMISTRY OF MATERIALS, 2009, 21 (20) :4796-4802
[8]   Microwave synthesis of graphene sheets supporting metal nanocrystals in aqueous and organic media [J].
Hassan, M. A. Hassan ;
Abdelsayed, Victor ;
Khder, Abd El Rahman S. ;
AbouZeid, Khaled M. ;
Terner, James ;
El-Shall, M. Samy ;
Al-Resayes, Saud I. ;
El-Azhary, Adel A. .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (23) :3832-3837
[9]   Nanocomposites of size-controlled gold nanoparticles and graphene oxide: Formation and applications in SERS and catalysis [J].
Huang, Jie ;
Zhang, Liming ;
Chen, Biao ;
Ji, Nan ;
Chen, Fenghua ;
Zhang, Yi ;
Zhang, Zhijun .
NANOSCALE, 2010, 2 (12) :2733-2738
[10]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339