Efficient synthesis ofβ-aminoketones catalyzed by Fe3O4@ quillaja sapogenin/Ni (II) as a novel magnetic nano-catalyst

被引:3
|
作者
Heidarpour, Majid [1 ]
Anaraki-Ardakani, Hossein [2 ]
Hasanzadeh, Neda [1 ]
Rayatzadeh, Ayeh [1 ]
机构
[1] Islamic Azad Univ, Dept Chem, Ahvaz Branch, Ahwaz, Iran
[2] Islamic Azad Univ, Mahshahr Branch, Dept Chem, Mahshahr, Iran
关键词
green chemistry; nano Fe3O4; nickel (II) chloride; quillaja saponin; three-component; 3-COMPONENT MANNICH REACTION; ACID CATALYSTS; AMINO KETONES; IONIC LIQUID; CELLULOSE; NANOPARTICLES; ALDEHYDES; SAPONIN;
D O I
10.1002/aoc.5834
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A new nano-magnetic core-shell Fe3O4@quillaja sapogenin/Ni (II) was synthesized and characterized thoroughly using various tests including energy-dispersive X-ray spectroscopy (EDS), Brunauer-Emmett-Teller (BET), thermo-gravimetric analysis (TGA), high-resolution transmission electron microscopy (HR-TEM), vibrating sample magnetometer (VSM), Fourier transform infrared (FT-IR) spectroscopy, inductively coupled plasma (ICP), X-ray diffraction (XRD) and scanning electron microscopy (SEM). The achievements demonstrated that the proposed agents were beneficial to synthesis the derivatives of beta-aminoketone. Moreover, it was possible to recover the catalyst by means of simple magnetic decantation quickly. Besides, no reduction in the activity of the catalyst occurred, even though it was utilized in various reactions.
引用
收藏
页数:13
相关论文
共 50 条