A new layered metal-organic framework as a promising heterogeneous catalyst for olefin epoxidation reactions

被引：142

作者：

Zhang, Jingming ^{[1
]}

Biradar, Ankush V. ^{[2
]}

Pramanik, Sanhita ^{[1
]}

Emge, Thomas J. ^{[1
]}

Asefa, Tewodros ^{[1
,2
]}

Li, Jing ^{[1
]}

机构：

[1] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA

[2] Rutgers State Univ, Dept Chem & Biochem Engn, Piscataway, NJ 08854 USA

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 52期

基金：

美国国家科学基金会;

关键词：

BUTYL HYDROPEROXIDE; STYRENE; NANOPARTICLES; OXIDATION; ALKENES; OXIDE; MOF;

D O I：

10.1039/c2cc18127d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new layered MOF material [Co(Hoba)(2)center dot 2H(2)O] (1) (H(2)oba = 4,4'-oxybis(benzoic acid)) has been synthesized and used as a highly recyclable heterogeneous catalyst for olefin epoxidation reactions. Both high conversion (96%) and high selectivity of epoxide products (96%) are achieved.

引用

页码：6541 / 6543

页数：3

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