Synthesis and Evaluation of a Photochromic Surfactant for Organic Reactions in Aqueous Media

被引：36

作者：

Drillaud, Nicolas ^{[1
]}

Banaszak-Leonard, Estelle ^{[1
]}

Pezron, Isabelle ^{[1
]}

Len, Christophe ^{[1
]}

机构：

[1] Univ Technol Compiegne, EA UTC ESCOM 4297, Ctr Rech Royallieu, F-60205 Compiegne, France

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 77卷 / 21期

关键词：

ACYLATION; AMINES; WATER; TELOMERIZATION; BUTADIENE; REARRANGEMENT; CLEAVAGE; KETONES; SYSTEM; MILD;

D O I：

10.1021/jo301466w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel photochromic azobenzene-based surfactant was described for organic chemistry in water. The molecule 4-butylazobenzyl-4'-triazologlucuronic acid sodium salt thus synthesized can be isomerized from its trans to its cis form reversibly in solution by simple light irradiation. That property allowed the recyclability of a model acetylation reaction performed in the surfactant media, compared to the well-known, commercially available sodium dodecyl sulfate surfactant media.

引用

页码：9553 / 9561

页数：9

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