Synthesis and Reactivity of a Transient, Terminal Nitrido Complex of Rhodium

被引：103

作者：

Scheibel, Markus G. ^{[1
]}

Wu, Yanlin ^{[1
]}

Stueckl, A. Claudia ^{[1
]}

Krause, Lennard ^{[1
]}

Carl, Elena ^{[1
]}

Stalke, Dietmar ^{[1
]}

de Bruin, Bas ^{[2
]}

Schneider, Sven ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

[2] Univ Amsterdam, Homogeneous & Supramol Catalysis Grp, Vant Hoff Inst Mol Sci HIMS, NL-1090 GD Amsterdam, Netherlands

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 47期

基金：

美国国家科学基金会;

关键词：

H BOND ACTIVATION; C-H; IRON; PHOTOLYSIS; CHEMISTRY; AMMONIA; COBALT; SHELL; OXO;

D O I：

10.1021/ja409764j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Irradiation of rhodium(II) azido complex [Rh(N-3){N(CHCHPtBu2)(2)}] allowed for the spectroscopic characterization of the first reported rhodium complex with a terminal nitrido ligand. DFT computations reveal that the unpaired electron of rhodium(IV) nitride complex [Rh(N){N(CHCHPtBu2)(2)}] is located in an antibonding Rh-N pi* bond involving the nitrido moiety, thus resulting in predominant N-radical character, in turn providing a rationale for its transient nature and observed nitride coupling to dinitrogen.

引用

页码：17719 / 17722

页数：4

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