Organometallic oxides: Preparation of the heterometallic (cyclopentadienyl)titanium-molybdenum oxide cluster [(eta-C5H5)Ti](2)[(eta-C5Me5)MoCl](mu(2)-O)(3)(mu(3)-O)

被引：5
|
作者：
Bottomley, F
McKenzieBoone, JE
机构：
[1] Department of Chemistry, University of New Brunswick, Fredericton
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 534卷 / 1-2期
基金：
加拿大自然科学与工程研究理事会;
关键词：
titanium; molybdenum; oxide clusters; cyclopentadienyls;
D O I：
10.1016/S0022-328X(96)06868-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction between (eta-C5H5)(5)Ti(CO)(2) and (eta-C5Me5)MoCl(O)(2) gave the heterometallic cluster [(eta(5)-C5H5)Ti](2)[(eta C5Me5)MoCl](mu(2)-O)(3)(mu(3)-O) (1). The formula and structure of 1 were proven by microanalysis, high resolution mass spectrometry, H-1 NMR and infrared spectroscopies. The two cluster electrons of diamagnetic 1 are localised in an orbital which is anti-bonding between the two titanium atoms.
引用
收藏
页码：23 / 25
页数：3
相关论文
共 50 条
  • [31] Cyclopentadienyl molybdenum dicarbonyl η3-allyl complexes as catalyst precursors for olefin epoxidation. Crystal structures of Cp′Mo(CO)2(η3-C3H5) (Cp′ = η5-C5H4Me, η5-C5Me5)
    Neves, Patricia
    Pereira, Claudia C. L.
    Paz, Filipe A. Almeida
    Gago, Sandra
    Pillinger, Martyn
    Silva, Carlos M.
    Valente, Anabela A.
    Romao, Carlos C.
    Goncalves, Isabel S.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2010, 695 (21) : 2311 - 2319
  • [32] Trinuclear heterometallic clusters with bridging disulfide and sulfide ligands [(mu(2)-S-2)(Cp*Ru)(2)(mu(3)-S)(mu(2)-S)(2)MS] derived from diruthenium complex [Cp*RuCl(mu(2)-Cl)(2)RuCp*Cl] and [MS(4)](2-) (M=W, Mo; Cp*=eta(5)-C(5)Me(5))
    Mizobe, Y
    Hosomizu, M
    Kubota, Y
    Hidai, M
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 507 (1-2) : 179 - 185
  • [33] Reactions of SmI2(THF)(x) with [Cp'Mo(CO)(3)]Hg-2(Cp'=C5H5- or C(5)Me(5)(-)): Crystal and molecular structures of [(THF)(4)I2Sm(mu-OC)Mo(CO)(2)(C5H5)] and [(C(5)Me(5))Mo(CO)(3)](2)
    Lin, GY
    Wong, WT
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 522 (02) : 271 - 275
  • [34] SYNTHESIS AND CHARACTERIZATION OF CHLOROBIS(DIALKYLAMIDO) AND ALKYLBIS(DIALKYLAMIDO) DERIVATIVES OF [(ETA(5)-C(5)ME(5))MCL(3)](M=TI,ZR)
    IRIGOYEN, AM
    MARTIN, A
    MENA, M
    PALACIOS, F
    YELAMOS, C
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 494 (1-2) : 255 - 259
  • [35] X-ray crystal structures on the hydrolysis path of [{Ti(C5Me4R)F3}2]:: Water adduct [{Ti(C5Me4Et)F3}2(H2O)]•(H2O), oxoaqua complex [Ti7F21O(C5Me4Et)5(H2O)2] and oxo complex [Ti8F22O2(C5Me4H)6]•2CHCl3
    Perdih, F
    Pevec, A
    Demsar, A
    JOURNAL OF FLUORINE CHEMISTRY, 2005, 126 (07) : 1065 - 1071
  • [36] Isocyanide insertion processes into the oxonitrido [{Ti(η5-C5Me5)(μ-O)}3(μ3-N)]
    Martin, Avelino
    Gonzalez-del Moral, Octavio
    Mena, Miguel
    Santamaria, Cristina
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2011, 67 : C610 - C610
  • [37] Discovering the chemical reactivity of the molecular oxonitride [{Ti(η5-C5Me5)(μ-O)}3(μ3-N)]
    Aguado-Ullate, Sonia
    Carbo, Jorge J.
    Gonzalez-del Moral, Octavio
    Gomez-Pantoja, Maria
    Hernan-Gomez, Alberto
    Martin, Avelino
    Mena, Miguel
    Poblet, Josep-M.
    Santamaria, Cristina
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (25) : 4011 - 4017
  • [38] SYNTHESIS AND CHARACTERIZATION OF ASYMMETRIC C,N-CYCLOMETALATED COMPLEXES OF MO(II) - X-RAY CRYSTAL-STRUCTURES OF [(ETA(5)-C5H(5))MO(C6H2-(OCH2O)-2,3-CH(2)NME(2)-(6))(I)(NO)] AND [(ETA(5)-C5H(5))MO(S-C6H4CH(ME)NME(2)-2)(I)(NO)]
    PFEFFER, M
    URRIOLABEITIA, EP
    DECIAN, A
    FISCHER, J
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 494 (1-2) : 187 - 193
  • [39] Synthesis and reactivity of the cycloheptatrienyl-bridged bimetallic complexes [M(CO)(3)(mu-eta(6):eta(1)-C7H7)M'(CO)(2)(eta-C(5)R(5))] (M=Cr, Mo or W; M'=Fe or Ru; R=H or Me)
    Davies, ES
    Whiteley, MW
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 519 (1-2) : 261 - 267
  • [40] Zwitterionic titanoxanes {Cp[η5-C5H4B(C6F5)3]Ti}2O and {(η5-iPrC5H4)[η5-1,3-iPrC5H3B(C6F5)3]Ti}2O as catalysts for cationic ring-opening polymerization
    Burlakov, VV
    Letov, AV
    Arndt, P
    Baumann, W
    Spannenberg, A
    Fischer, C
    Strunkina, LI
    Minacheva, MK
    Vygodskii, YS
    Rosenthal, U
    Shur, VB
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 200 (1-2) : 63 - 67
12345