Organometallic oxides: Preparation of the heterometallic (cyclopentadienyl)titanium-molybdenum oxide cluster [(eta-C5H5)Ti](2)[(eta-C5Me5)MoCl](mu(2)-O)(3)(mu(3)-O)

被引：5

作者：

Bottomley, F

McKenzieBoone, JE

机构：

[1] Department of Chemistry, University of New Brunswick, Fredericton

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 534卷 / 1-2期

基金：

加拿大自然科学与工程研究理事会;

关键词：

titanium; molybdenum; oxide clusters; cyclopentadienyls;

D O I：

10.1016/S0022-328X(96)06868-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between (eta-C5H5)(5)Ti(CO)(2) and (eta-C5Me5)MoCl(O)(2) gave the heterometallic cluster [(eta(5)-C5H5)Ti](2)[(eta C5Me5)MoCl](mu(2)-O)(3)(mu(3)-O) (1). The formula and structure of 1 were proven by microanalysis, high resolution mass spectrometry, H-1 NMR and infrared spectroscopies. The two cluster electrons of diamagnetic 1 are localised in an orbital which is anti-bonding between the two titanium atoms.

引用

页码：23 / 25

页数：3

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