Organometallic oxides: Preparation of the heterometallic (cyclopentadienyl)titanium-molybdenum oxide cluster [(eta-C5H5)Ti](2)[(eta-C5Me5)MoCl](mu(2)-O)(3)(mu(3)-O)

被引：5

作者：

Bottomley, F

McKenzieBoone, JE

机构：

[1] Department of Chemistry, University of New Brunswick, Fredericton

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 534卷 / 1-2期

基金：

加拿大自然科学与工程研究理事会;

关键词：

titanium; molybdenum; oxide clusters; cyclopentadienyls;

D O I：

10.1016/S0022-328X(96)06868-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between (eta-C5H5)(5)Ti(CO)(2) and (eta-C5Me5)MoCl(O)(2) gave the heterometallic cluster [(eta(5)-C5H5)Ti](2)[(eta C5Me5)MoCl](mu(2)-O)(3)(mu(3)-O) (1). The formula and structure of 1 were proven by microanalysis, high resolution mass spectrometry, H-1 NMR and infrared spectroscopies. The two cluster electrons of diamagnetic 1 are localised in an orbital which is anti-bonding between the two titanium atoms.

引用

页码：23 / 25

页数：3

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[1] Organometallic oxides: preparation of the heterometallic (cyclopentadienyl) titanium-molybdenum oxide cluster [(eta-C5H5)Ti]2[ (eta-C5 Me5) MoCl](ae2-O)3 (ae3-O)
Bottomley, F.
McKenzie-Boone, J. E.
Journal of Organometallic Chemistry, 534 (1-2):
[2] ORGANOMETALLIC OXIDES - CONVENIENT, HIGH-YIELD SYNTHESES OF THE (PENTAMETHYLCYCLOPENTADIENYL)MOLYBDENUM OXO COMPLEXES (ETA-C5ME5)MOCL(O)2, ANTI-[(ETA-C5ME5)MOCL(O)]2(MU-O), (ETA-C5ME5)MOCL2(O), AND SYN-[(ETA-C5ME5)MO(O)(MU-O)]2
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[5] Organometallic selenides: Preparation of [(eta-C5H5)Ti(mu(3)-Se)](7) and [(eta-C5H5)Ti](5)(mu(3)-Se)(6) by reduction of [(eta-C5H5)Ti](4)(mu(2)-Se)(3)(mu 3-Se)(3) with Bu(3)(n)SnH and preparation of [(eta-C5H5)Ti](5)(mu(3)-Se)(6) by oxidation of (eta-C5H5)TiCl2 with H2Se
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[6] ORGANOMETALLIC OXIDES AND SULFIDES - PREPARATION OF [(ETA-C5H5)TI]5(MU-3-S)6, [(ETA-C5H5)TI]5(MU-3-S)5(MU-3-S2)(MU-4-O), AND (ETA-C5H5)2TI(SH)(MU-O)TI(ETA-C5H5)(MU-S)2-TI(ETA-C5H5)2 BY REDUCTIVE AGGREGATION OF (ETA-C5H5)2TI(SH)2 WITH ZINC POWDER OR BY OXIDATION OF (ETA-C5H5)2TI(CO)2 WITH H2S IN THE PRESENCE OF WATER
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[9] PREPARATION AND PROPERTIES OF (ETA-C5H5)2TICL(SEH), (ETA-C5H5)2TI(SEH)2, [(ETA-C5H5)TI]4(MU-2-SE)3(MU-3-SE)3, AND RELATED CYCLOPENTADIENYL SELENIDES OF TITANIUM
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