Effect of mineral matter on structure and dielectric properties of chars

被引:23
作者
Liu, Haiyu [1 ]
Xu, Liang [1 ]
Jin, Yan [1 ]
Fan, Baoguo [1 ]
Qiao, Xiaolei [1 ]
Yang, Yanxia [1 ]
机构
[1] Taiyuan Univ Technol, Sch Elect & Power Engn, Taiyuan 030024, Shanxi, Peoples R China
基金
中国国家自然科学基金;
关键词
Dielectric property; Mineral matter; Phase transformation; Coal char; VICTORIAN BROWN-COAL; CARBOTHERMAL REDUCTION; BITUMINOUS COAL; SILICON-CARBIDE; HEAT-TREATMENT; MICROWAVE; PYROLYSIS; REACTIVITY; COMBUSTION; CARBON;
D O I
10.1016/j.fuel.2018.02.161
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The study was undertaken to investigate the changes of mineral matters in coal during heat treatment and its effect on structure and dielectric properties of generated chars. An acid treatment method was adopted to remove mineral matters in coal for preparing chars at 850-1600 degrees C using an electric furnace. Dielectric properties of coal chars were determined with the transmission/reflection method. Also, phase structure of coal chars was examined by X-ray diffraction (XRD). Significant transformation was found in the presence of mineral matters during heat treatment. Especially the process of creating silicon carbide (SiC) above 1300 degrees C in carbothermal reduction played a catalytic role on char structure. Consequently, dielectric properties were improved with the increase of structural ordering. These results could be instructive for the application of mineral matters in microwave technique at higher temperatures.
引用
收藏
页码:370 / 374
页数:5
相关论文
共 29 条
[1]   Microwave-assisted leaching - a review [J].
Al-Harahsheh, M ;
Kingman, SW .
HYDROMETALLURGY, 2004, 73 (3-4) :189-203
[2]   Factors affecting the microwave coking of coals and the implications on microwave cavity design [J].
Binner, Eleanor ;
Mediero-Munoyerro, Maria ;
Huddle, Thomas ;
Kingman, Sam ;
Dodds, Chris ;
Dimitrakis, Georgios ;
Robinson, John ;
Lester, Ed .
FUEL PROCESSING TECHNOLOGY, 2014, 125 :8-17
[3]   Kinetics of synthesis of silicon carbide by carbothermal reduction of silicon dioxide [J].
Chen, CY ;
Lin, CI ;
Chen, SH .
BRITISH CERAMIC TRANSACTIONS, 2000, 99 (02) :57-62
[4]  
Cheng D. K., 1989, FIELD WAVE ELECTROMA
[5]   EVOLUTION OF CHAR CHEMISTRY, CRYSTALLINITY, AND ULTRAFINE STRUCTURE DURING PULVERIZED-COAL COMBUSTION [J].
DAVIS, KA ;
HURT, RH ;
YANG, NYC ;
HEADLEY, TJ .
COMBUSTION AND FLAME, 1995, 100 (1-2) :31-40
[6]   Structural ordering of coal char during heat treatment and its impact on reactivity [J].
Feng, B ;
Bhatia, SK ;
Barry, JC .
CARBON, 2002, 40 (04) :481-496
[7]   MICROWAVE AND CONVENTIONAL PYROLYSIS OF A BITUMINOUS COAL [J].
GASNER, LL ;
DENLOYE, AO ;
REGAN, TM .
CHEMICAL ENGINEERING COMMUNICATIONS, 1986, 48 (4-6) :349-354
[8]   Variation of Char Structure during Anthracite Pyrolysis Catalyzed by Fe2O3 and Its Influence on Char Combustion Reactivity [J].
Gong, Xuzhong ;
Guo, Zhancheng ;
Wang, Zhi .
ENERGY & FUELS, 2009, 23 (09) :4547-4552
[9]   Dielectric relaxation in solids [J].
Jonscher, AK .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1999, 32 (14) :R57-R70
[10]   Dielectric properties and temperature profile of fly ash-based geopolymer mortar [J].
Jumrat, Saysunee ;
Chatveera, Burachat ;
Rattanadecho, Phadungsak .
INTERNATIONAL COMMUNICATIONS IN HEAT AND MASS TRANSFER, 2011, 38 (02) :242-248