Uniform manganese hexacyanoferrate hydrate nanocubes featuring superior performance for low-cost supercapacitors and nonenzymatic electrochemical sensors

被引：101
作者：
Pang, Huan [1 ,2 ]
Zhang, Yizhou [2 ]
Cheng, Tao [2 ]
Lai, Wen-Yong [2 ]
Huang, Wei [2 ]
机构：
[1] Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China
[2] Nanjing Univ Posts & Telecommun, Natl Jiangsu Synerget Innovat Ctr Adv Mat SICAM, Inst Adv Mat, Key Lab Organ Elect & Informat Displays, Nanjing 210023, Jiangsu, Peoples R China
来源：
NANOSCALE | 2015年 / 7卷 / 38期
基金：
中国国家自然科学基金;
关键词：
PRUSSIAN-BLUE; BATTERY ELECTRODES; HYDROGEN-PEROXIDE; NANOPARTICLES; FRAMEWORK; CATHODE; ELECTROCATALYSIS; NANOSTRUCTURES; STORAGE; DESIGN;
D O I：
10.1039/c5nr04322k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Uniform manganese hexacyanoferrate hydrate nanocubes are prepared via a simple chemical precipitation method at room temperature. Due to both micro/mesopores of the Prussian blue analogue and nanocubic structures, the manganese hexacyanoferrate hydrate nanocubes allow the efficient charge transfer and mass transport for electrolyte solution and chemical species. Thus, the manganese hexacyanoferrate hydrate nanocube electrode shows a good rate capability and cycling stability for electrochemical capacitors. Furthermore, electrodes modified with manganese hexacyanoferrate hydrate nanocubes demonstrate a sensitive electrochemical response to hydrogen peroxide (H2O2) in buffer solutions with a high selectivity.
引用
收藏
页码：16012 / 16019
页数：8
相关论文
共 59 条
[1]   MORPHOLOGICAL VARIATION AT THE [NIFE(CN)6]2-/- DERIVATIZED NICKEL ELECTRODE - A TECHNIQUE FOR THE EVALUATION OF ALKALI CATION CONTAINING SOLUTIONS [J].
AMOS, LJ ;
DUGGAL, A ;
MIRSKY, EJ ;
RAGONESI, P ;
BOCARSLY, AB ;
FITZGERALDBOCARSLY, PA .
ANALYTICAL CHEMISTRY, 1988, 60 (03) :245-249
[2]   Fabrication of a Cyanide-Bridged Coordination Polymer Electrode for Enhanced Electrochemical Ion Storage Ability [J].
Asakura, Daisuke ;
Okubo, Masashi ;
Mizuno, Yoshifumi ;
Kudo, Tetsuichi ;
Zhou, Haoshen ;
Ikedo, Kazumichi ;
Mizokawa, Takashi ;
Okazawa, Atsushi ;
Kojima, Norimichi .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (15) :8364-8369
[3]   Following the Biocatalytic Activities of Glucose Oxidase by Electrochemically Cross-Linked Enzyme-Pt Nanoparticles Composite Electrodes [J].
Bahshi, Lily ;
Frasconi, Marco ;
Tel-Vered, Ran ;
Yehezkeli, Omer ;
Willner, Itamar .
ANALYTICAL CHEMISTRY, 2008, 80 (21) :8253-8259
[4]   Metal hexacyanoferrates: Electrosynthesis, in situ characterization, and applications [J].
de Tacconi, NR ;
Rajeshwar, K ;
Lezna, RO .
CHEMISTRY OF MATERIALS, 2003, 15 (16) :3046-3062
[5]   Multiple-color electrochromism from layer-by-layer-assembled polyaniline/Prussian Blue nanocomposite thin films [J].
DeLongchamp, DM ;
Hammond, PT .
CHEMISTRY OF MATERIALS, 2004, 16 (23) :4799-4805
[6]   Improved Sensing in Physiological Buffers by Controlling the Nanostructure of Prussian Blue Films [J].
Du, Jie ;
Wang, Yanfeng ;
Zhou, Xibin ;
Xue, Zhonghua ;
Liu, Xiuhui ;
Sun, Kun ;
Lu, Xiaoquan .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (35) :14786-14793
[7]   Direct electrochemistry and electrocatalysis of heme proteins immobilized on gold nanoparticles stabilized by chitosan [J].
Feng, JJ ;
Zhao, G ;
Xu, JJ ;
Chen, HY .
ANALYTICAL BIOCHEMISTRY, 2005, 342 (02) :280-286
[8]   Cathodic deposition of Ni(OH)2 and Co(OH)2 for asymmetric supercapacitors: Importance of the electrochemical reversibility of redox couples [J].
Hu, Chi-Chang ;
Chen, Jia-Cing ;
Chang, Kuo-Hsin .
JOURNAL OF POWER SOURCES, 2013, 221 :128-133
[9]   Magnetically separable Prussian blue analogue Mn3[Co(CN)6]2•nH2O porous nanocubes as excellent absorbents for heavy metal ions [J].
Hu, Lin ;
Mei, Ji-yang ;
Chen, Qian-wang ;
Zhang, Ping ;
Yan, Nan .
NANOSCALE, 2011, 3 (10) :4270-4274
[10]   Prussian Blue Analogue Mn3[Co(CN)6]2•nH2O porous nanocubes: large-scale synthesis and their CO2 storage properties [J].
Hu, Lin ;
Zhang, Ping ;
Chen, Qian-wang ;
Yan, Nan ;
Mei, Ji-yang .
DALTON TRANSACTIONS, 2011, 40 (20) :5557-5562
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