Uniform manganese hexacyanoferrate hydrate nanocubes featuring superior performance for low-cost supercapacitors and nonenzymatic electrochemical sensors

被引:100
作者
Pang, Huan [1 ,2 ]
Zhang, Yizhou [2 ]
Cheng, Tao [2 ]
Lai, Wen-Yong [2 ]
Huang, Wei [2 ]
机构
[1] Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China
[2] Nanjing Univ Posts & Telecommun, Natl Jiangsu Synerget Innovat Ctr Adv Mat SICAM, Inst Adv Mat, Key Lab Organ Elect & Informat Displays, Nanjing 210023, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
PRUSSIAN-BLUE; BATTERY ELECTRODES; HYDROGEN-PEROXIDE; NANOPARTICLES; FRAMEWORK; CATHODE; ELECTROCATALYSIS; NANOSTRUCTURES; STORAGE; DESIGN;
D O I
10.1039/c5nr04322k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Uniform manganese hexacyanoferrate hydrate nanocubes are prepared via a simple chemical precipitation method at room temperature. Due to both micro/mesopores of the Prussian blue analogue and nanocubic structures, the manganese hexacyanoferrate hydrate nanocubes allow the efficient charge transfer and mass transport for electrolyte solution and chemical species. Thus, the manganese hexacyanoferrate hydrate nanocube electrode shows a good rate capability and cycling stability for electrochemical capacitors. Furthermore, electrodes modified with manganese hexacyanoferrate hydrate nanocubes demonstrate a sensitive electrochemical response to hydrogen peroxide (H2O2) in buffer solutions with a high selectivity.
引用
收藏
页码:16012 / 16019
页数:8
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