[Ga2Cl4(dioxane)2]x:: molecular structure and reactivity of a polymeric gallium(II) halide containing two five-coordinate gallium atoms about a Ga-Ga bond

被引：21

作者：

Wei, PR ^{[1
]}

Li, XW ^{[1
]}

Robinson, GH ^{[1
]}

机构：

[1] Univ Georgia, Dept Chem, Athens, GA 30602 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 14期

关键词：

D O I：

10.1039/a903166i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A polymeric 1,4-dioxane adduct of gallium(II) chloride, [Ga2Cl4(dioxane)(2)](x), containing two five-coordinate gallium atoms about a Ga-Ga bond [Ga-Ga 2.3825(9) Angstrom] reacts with 1,4-dilithiotetraphenylbutadiene affording an unusual Ga(II)-tetraphenylbutadiene complex.

引用

页码：1287 / 1288

页数：2

共 37 条

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[35] Structure-dependent spectral behavior of five-coordinate ternary copper(II) complexes containing 2,2′-dipicolylamine.: X-ray crystal structures of [Cu(dpa)(pic)]ClO4, and [Cu(dpa)(pic)]PF6•H2O (dpa=2,2′-dipicolylamine, pic=picolinate)
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