[Ga2Cl4(dioxane)2]x:: molecular structure and reactivity of a polymeric gallium(II) halide containing two five-coordinate gallium atoms about a Ga-Ga bond

被引：21
|
作者：
Wei, PR [1 ]
Li, XW [1 ]
Robinson, GH [1 ]
机构：
[1] Univ Georgia, Dept Chem, Athens, GA 30602 USA
来源：
CHEMICAL COMMUNICATIONS | 1999年 / 14期
关键词：
D O I：
10.1039/a903166i
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A polymeric 1,4-dioxane adduct of gallium(II) chloride, [Ga2Cl4(dioxane)(2)](x), containing two five-coordinate gallium atoms about a Ga-Ga bond [Ga-Ga 2.3825(9) Angstrom] reacts with 1,4-dilithiotetraphenylbutadiene affording an unusual Ga(II)-tetraphenylbutadiene complex.
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页码：1287 / 1288
页数：2
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