Excess enthalpy, density, and speed of sound for the mixtures β-pinene plus 1-butanol or 2-butanol at (283.15, 298.15, and 313.15) K

被引:16
作者
Langa, E [1 ]
Mainar, AM [1 ]
Pardo, JI [1 ]
Urieta, JS [1 ]
机构
[1] Univ Zaragoza, GATHERS, Aragon Inst Engn Res I3A, Fac Ciencias, E-50009 Zaragoza, Spain
关键词
D O I
10.1021/je050294+
中图分类号
O414.1 [热力学];
学科分类号
摘要
Excess enthalpies, densities, and speeds of sound at the temperatures (283.15, 298.15, and 313.15) K are reported for the binary mixtures beta-pinene + ethanol and beta-pinene + 1-propanol. Excess molar volumes, speed of sound deviations, isentropic compressibilities, and excess isentropic compressibilities have been calculated from the densities and speeds of sound. The excess isentropic compressibilities have been fitted to Redlich-Kister polynomials whereas the remaining excess properties and deviations of properties have been fitted to Pade approximants. Excess properties are positive for both mixtures while speed of sound deviations show negative values. The values of these properties are discussed in terms of the molecular interactions. The enthalpic and volumetric behaviors of the mixtures are compared with those of the mixtures of beta-pinene with ethanol and 1-propanol and of the mixtures of the butanols with cyclohexane.
引用
收藏
页码:392 / 397
页数:6
相关论文
共 50 条
[31]   GENERALIZED CORRESPONDING STATES PRINCIPLE .1. EXCESS VOLUMES FOR BINARY-MIXTURES OF ACETONITRILE WITH 1-BUTANOL AND 2-BUTANOL [J].
CONTRERAS, M .
BOLETIN DE LA SOCIEDAD CHILENA DE QUIMICA, 1990, 35 (04) :349-358
[32]   Viscosities of the ternary mixture (1-butanol plus n-hexane plus 1-chlorobutane) at 298.15 K and 313.15 K [J].
Dominguez, M ;
Santafe, J ;
Lopez, MC ;
Royo, FM ;
Urieta, JS .
FLUID PHASE EQUILIBRIA, 1998, 152 (01) :133-148
[33]   (Liquid plus liquid) equilibrium of {water plus phenol + (1-butanol, or 2-butanol, or tert-butanol)} systems [J].
de Oliveira, Leonardo Hadlich ;
Aznar, Martin .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2010, 42 (11) :1379-1385
[34]   Densities and volumetric properties of (N-(2-hydroxyethyl)morpholine plus ethanol,+1-propanol,+2-propanol,+1-butanol, and +2-butanol) at (293.15, 298.15, 303.15, 313.15, and 323.15) K [J].
Awwad, Akl M. ;
Alsyouri, Hatem M. ;
Abu-Daabes, Malyuba A. ;
Jbara, Kifah A. .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2008, 40 (04) :592-598
[35]   Excess enthalpy, density, and speed of sound determination for the ternary mixture (methyl tert-butyl ether plus 1-butanol plus n-hexane) [J].
Mascato, Eva ;
Mariano, Alejandra ;
Pineiro, Manuel M. ;
Luis Legido, Jose ;
Paz Andrade, M. I. .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2007, 39 (09) :1247-1256
[36]   Volumetric and acoustic properties of the ternary mixture 1-butanol+1-chlorobutane plus tetrahydrofuran at 283.15, 298.15, and 313.15 K [J].
Valén, A ;
Gascón, I ;
Lafuente, C ;
Urieta, JS ;
Royo, FM ;
Postigo, M .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2002, 23 (06) :1587-1598
[37]   Volumetric and ultrasonic study of mixtures of 2-phenylethanol with 1-butanol, 2-butanol, and 2-methyl-1-butanol at T = (298.15-323.15) K and atmospheric pressure: Measurement and prediction [J].
Papari, M. M. ;
Ghodrati, H. ;
Fadaei, F. ;
Sadeghi, R. ;
Behrouz, S. ;
Rad, M. N. Soltani ;
Moghadasi, J. .
JOURNAL OF MOLECULAR LIQUIDS, 2013, 180 :121-128
[38]   Relative permittivities of binary mixtures of 1-butanol plus n-alkane AT 298.15 K [J].
de Cominges, BE ;
Piñeiro, MM ;
Mascato, E ;
Mosteiro, L ;
Iglesias, TP ;
Legido, JL .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2003, 72 (01) :129-133
[39]   Vapour pressures at several temperatures, and excess functions at T = 298.15 K of (butanone plus 2-butanol) [J].
Garriga, R ;
Martínez, S ;
Pérez, P ;
Gracia, M .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1999, 31 (01) :117-127
[40]   VAPOR-PRESSURES AND EXCESS GIBBS ENERGIES IN MIXTURES OF A PYRIDINE BASE + 2-PROPANOL, + 2-BUTANOL, + I-BUTANOL, AND + TERT-BUTANOL AT 313.15 K [J].
WARYCHA, S .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1977, 9 (09) :813-820