catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ2N:N′] bis(perchlorate) 4,4′-bipyridine disolvate dihydrate]

被引：1

作者：

Nettleman, Joseph H. ^{[1
]}

LaDuca, Robert L. ^{[1
]}

机构：

[1] Michigan State Univ, Dept Chem, Lyman Briggs Coll, E Lansing, MI 48825 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

关键词：

D O I：

10.1107/S1600536808035125

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, {[Co(C10H8N2)(H2O)4](ClO4)(2)center dot-2C(10)H(8)N(2) center dot 2H(2)O}(n), slightly distorted octahedrally coordinated Co-II ions situated on inversion centers are linked into polycationic chains through 4,4'-bipyridine tethering ligands. These are connected into supramolecular layers by hydrogen bonding involving aqua ligands, perchlorate anions and uncoordinated water molecules. A twofold interpenetrated primitive cubic supramolecular network is formed by the interaction of pseudo-layers by hydrogen bonding between aqua ligands and unligated 4,4 '-bipyridine molecules.

引用

页码：M1485 / U1291

页数：13