Radiation-induced crosslinking of acetylene-impregnated polyesters

被引:11
作者
Jones, RA [1 ]
Punyodom, W [1 ]
Ward, IM [1 ]
Johnson, AF [1 ]
机构
[1] Univ Leeds, Dept Phys & Astron, IRC Polymer Sci & Technol, Leeds LS2 9JT, W Yorkshire, England
关键词
enhanced crosslinking; polyesters; PET; PBT; PCT; acetylene impregnation; irradiation;
D O I
10.1016/S0168-583X(01)00812-6
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Enhanced crosslinking and reduction in chain scission are found in the amorphous regions of polycrystalline polyesters, when they are irradiated in the presence of acetylene, Increasing the chain length of the alkyl moiety is also found to decrease the extent of damaging main chain scission. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:163 / 168
页数:6
相关论文
共 14 条
[1]   EFFECTS OF IONIZING-RADIATION ON LINEAR AROMATIC POLYESTERS [J].
BELL, VL ;
PEZDIRTZ, GF .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1983, 21 (11) :3083-3092
[2]   ESR STUDY OF FREE RADICALS FORMED BY GAMMA-IRRADIATION OF POLY(ETHYLENE TEREPHTHALATE) [J].
CAMPBELL, D ;
ARAKI, K ;
TURNER, DT .
JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1966, 4 (10PA) :2597-&
[3]   POST-IRRADIATION FREE-RADICAL REACTIONS IN POLY(ETHYLENE TEREPHTHALATE) [J].
CAMPBELL, D ;
MONTEITH, LK ;
TURNER, DT .
JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1970, 8 (09) :2703-&
[4]   RADIATION-INDUCED CROSS-LINKING OF POLYETHYLENE IN THE PRESENCE OF ACETYLENE - A GEL FRACTION, UV-VISIBLE, AND ESR SPECTROSCOPY STUDY [J].
JONES, RA ;
SALMON, GA ;
WARD, IM .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1993, 31 (07) :807-819
[5]   Gel fractions and chain reactions in irradiated polyethylenes [J].
Jones, RA ;
Groves, DJ ;
Ward, IM ;
Taylor, DJR ;
Stepto, RFT .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1999, 151 (1-4) :213-217
[6]   Reactions of amorphous PE radical-pairs in vacuo and in acetylene: A comparison of gel fraction data with Flory-Stockmayer and atomistic modelling analyses [J].
Jones, RA ;
Ward, IM ;
Taylor, DJR ;
Stepto, RFT .
POLYMER, 1996, 37 (16) :3643-3657
[7]   Atomistic and Flory-Stockmayer analyses of irradiated i-PP gel fractions and comparison with results from PE [J].
Jones, RA ;
Cail, JI ;
Stepto, RFT ;
Ward, IM .
MACROMOLECULES, 2000, 33 (20) :7337-7344
[8]   STRUCTURE AND MORPHOLOGY OF HIGHLY ORIENTED RADIATION CROSS-LINKED POLYETHYLENE FIBERS [J].
KLEIN, PG ;
GONZALEZOROZCO, JA ;
WARD, IM .
POLYMER, 1991, 32 (10) :1732-1736
[9]  
KNOLLE W, 1999, IONIZING RAD POLYM, P213
[10]   Comparative wear under four different tribological conditions of acetylene enhanced cross-linked ultra high molecular weight polyethylene [J].
Marrs, H ;
Barton, DC ;
Jones, RA ;
Ward, IM ;
Fisher, J ;
Doyle, C .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 1999, 10 (06) :333-342