Temperature-modulated photoluminescence of quantum dots

被引：29

作者：

Hou, Yi ^{[1
]}

Ye, Jing ^{[1
,3
]}

Gui, Zhou ^{[2
]}

Zhang, Guangzhao ^{[1
]}

机构：

[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China

[2] Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Peoples R China

[3] Chinese Univ Hong Kong, Dept Chem, Shatin, Hong Kong, Peoples R China

来源：

LANGMUIR | 2008年 / 24卷 / 17期

关键词：

D O I：

10.1021/la800312u

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cadmium sulfide (CdS) quantum dots (QDs) grafted with thermoresponsive poly(N-isopropylacrylamide) chains have been prepared. As the temperature increases, PNIPAM chains shrink and aggregate so that the QDs exhibit enhanced fluorescence emission. At a temperature around the lower critical solution temperature (LCST) of PNIPAM, the fluorescence exhibits a maximum intensity. Our experiments reveal that the fluorescence emission is determined by the interactions between QDs as a function of the interdot distance. The optical interdot distance for the maximum luminescence intensity is similar to 10 nm. The chain length of PNIPAM also has an effect on the luminescence. Short PNIPAM chains are difficult to associate, leading to a large interdot distance. so that the luminescence intensity changes slightly with temperature.

引用

页码：9682 / 9685

页数：4

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