High-sensitivity and high-spatial-resolution imaging of self-assembled monolayer on platinum using radially polarized beam excited second-harmonic-generation microscopy

被引：7

作者：

Hashimoto, Mamoru ^{[1
]}

Niioka, Hirohiko ^{[1
]}

Ashida, Koichiro ^{[1
]}

Yoshiki, Keisuke ^{[2
]}

Araki, Tsutomu ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Toyonaka, Osaka 5608531, Japan

[2] Univ Hyogo, Grad Sch Engn, Himeji, Hyogo 6712201, Japan

来源：

APPLIED PHYSICS EXPRESS | 2015年 / 8卷 / 11期

基金：

中国国家自然科学基金;

关键词：

GENERATION; LIGHT; DEVICES;

D O I：

10.7567/APEX.8.112401

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

High-sensitivity, high-spatial-resolution imaging of organic monolayers on platinum with second harmonic generation (SHG) microscopy using radially polarized beam excitation is investigated. A tightly focused, radially polarized beam forms a longitudinal electric field at the focus. The longitudinal field is enhanced at a metal surface and increases the intensity of SHG from the molecules on the metal surface. The SHG signal from a self-assembled monolayer (SAM) on a platinum surface excited by a radially polarized beam is approximately 3.7 times higher than that obtained with a linearly polarized beam. Improved spatial resolution is also demonstrated using a SAM patterned by electron beam lithography. (C) 2015 The Japan Society of Applied Physics

引用

页数：4

共 25 条

[1] Nearly 100% internal phosphorescence efficiency in an organic light-emitting device [J].

Adachi, C ;

Baldo, MA ;

Thompson, ME ;

Forrest, SR .

JOURNAL OF APPLIED PHYSICS, 2001, 90 (10) :5048-5051

[2] Contact resistance in metal-molecule-metal junctions based on aliphatic SAMs: Effects of surface linker and metal work function [J].

Beebe, JM ;

Engelkes, VB ;

Miller, LL ;

Frisbie, CD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (38) :11268-11269

[3] Polarization-vortex-driven second-harmonic generation [J].

Biss, DP ;

Brown, TG .

OPTICS LETTERS, 2003, 28 (11) :923-925

[4] Cylindrical vector beam focusing through a dielectric interface [J].

Biss, DP ;

Brown, TG .

OPTICS EXPRESS, 2001, 9 (10) :490-497

[5] Submonolayer island nucleation and growth kinetics during self-assembled monolayer formation [J].

Doudevski, I ;

Hayes, WA ;

Schwartz, DK .

PHYSICAL REVIEW LETTERS, 1998, 81 (22) :4927-4930

[6] INFRARED STUDY OF ADSORBED MOLECULES ON METAL SURFACES BY REFLECTION TECHNIQUES [J].

GREENLER, RG .

JOURNAL OF CHEMICAL PHYSICS, 1966, 44 (01) :310-&

[7] Enhancement of second-harmonic generation from self-assembled monolayers on gold by excitation with a radially polarized beam [J].

Hashimoto, Mamoru ;

Ashida, Koichiro ;

Yoshiki, Keisuke ;

Araki, Tsutomu .

OPTICS LETTERS, 2009, 34 (09) :1423-1425

[8] INFRARED REFLECTION-ABSORPTION SPECTROSCOPY OF ADSORBED MOLECULES [J].

Hoffmann, Friedrich M. .

SURFACE SCIENCE REPORTS, 1983, 3 (2-3) :107-192

[9] Organic thin film transistors: From theory to real devices [J].

Horowitz, G .

JOURNAL OF MATERIALS RESEARCH, 2004, 19 (07) :1946-1962

[10] Improvement of lateral resolution and extension of depth of field in two-photon microscopy by a higher-order radially polarized beam [J].

Ipponjima, Sari ;

Hibi, Terumasa ;

Kozawa, Yuichi ;

Horanai, Hibiki ;

Yokoyama, Hiroyuki ;

Sato, Shunichi ;

Nemoto, Tomomi .

MICROSCOPY, 2014, 63 (01) :23-32

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