A water-tolerant C16H3PW11CrO39 catalyst for the efficient conversion of monosaccharides into 5-hydroxymethylfurfural in a micellar system

被引：29

作者：

Zheng, Hongwei ^{[1
]}

Sun, Zhong ^{[1
]}

Yi, Xiaohu ^{[1
]}

Wang, Shengtian ^{[1
]}

Li, Jianxin ^{[1
]}

Wang, Xiaohong ^{[1
]}

Jiang, Zijiang ^{[2
]}

机构：

[1] NE Normal Univ, Fac Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Peoples R China

[2] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China

来源：

RSC ADVANCES | 2013年 / 3卷 / 45期

基金：

中国国家自然科学基金;

关键词：

HETEROPOLYACID SALT; IONIC LIQUID; FRUCTOSE; ACID; DEHYDRATION; GLUCOSE; BIOMASS; TRANSFORMATIONS; OXIDATION;

D O I：

10.1039/c3ra43408g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A water-tolerant cetyltrimethyl ammonium salt of transition metal (Cr(III)) substituted polyoxometalate C16H3PW11CrO39 (C-16 = cetyltrimethyl ammonium) has been designed and used for the conversion of fructose and glucose into 5-hydroxymethylfurfural (HMF). The catalyst shows high conversion efficiency (90.3% and 84.2%, respectively) and high yields (40.6% and 35.2%, respectively) due to its dual acidity and hydrophobicity. The catalyst is stable during an aqueous-phase reaction and can be recycled via a simple separation process.

引用

页码：23051 / 23056

页数：6

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