Einstein A coefficients for rovibronic lines of the A 2 → X 2Σ+ and B' 2Σ+→ X 2 Σ+ transitions of MgH

Einstein A coefficients have been calculated for rovibronic lines of the A (2) -> X (2)Sigma(+) and B-' (2)Sigma(+) -> X (2)Sigma(+) transitions of (MgH)-Mg-24. Using the experimentally determined analytic potential energy curve for the X (2)Sigma(+)state, and the Rydberg-Klein-Rees potentials for the A (2) and B-' (2)Sigma(+)states, combined with the most recent ab initio transition dipole moments, rovibronic transition moments were computed. The rovibronic transition frequencies were obtained accurately by subtracting the published term values of the X (2)Sigma(+), A (2) and B-' (2)Sigma(+) states. Using the rovibronic transition dipole moments, transition frequencies and the Honl-London factors, the Einstein A coefficients were calculated individually for similar to 30 000 rovibronic lines of the A (2) -> X (2)Sigma(+) and B-' (2)Sigma(+) -> X (2)Sigma(+) transitions of (MgH)-Mg-24.