Glycosylation of Stannyl Ceramides Promoted by Modified Montmorillonite in Supercritical Carbon Dioxide

被引：3
作者：
Antonio Morales-Serna, Jose [1 ]
Nguyen, Bao N. [2 ]
Garcia-Rios, Erendira [3 ]
Gavino, Ruben [3 ]
Cardenas, Jorge [3 ]
Garcia de la Mora, Gustavo [4 ]
机构：
[1] Univ Autonoma Metropolitana Iztapalapa, Dept Quim, Av San Rafael Atlixco 186, Ciudad De Mexico 09340, Mexico
[2] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England
[3] Univ Nacl Autonoma Mexico, Inst Quim, Ciudad Univ, Ciudad De Mexico 04510, Mexico
[4] Univ Nacl Autonoma Mexico, Dept Quim Organ, Fac Quim, Ciudad Univ, Ciudad De Mexico 04510, Mexico
来源：
SYNTHESIS-STUTTGART | 2018年 / 50卷 / 03期
关键词：
glycosylation; beta-glycolipids; iGB3; supercritical carbon dioxide; montmorillonite; FLUID EXTRACTION; GREEN SOLVENTS; ACID; GLYCOSIDATION; CATALYSIS; SUGAR; CO2; GLYCOLIPIDS; SOLUBILITY; EFFICIENT;
D O I：
10.1055/s-0036-1591515
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The direct glycosylation of ceramides in supercritical carbon dioxide (scCO(2)) successfully proceeded to produce beta-glycolipids in high yield and with full stereoselectivity. The reaction is promoted by montmorillonite modified with a superacid (CF3SO3H). The value of this protocol was demonstrated in the efficient synthesis of isoglobotrihexosylceramide (iGB(3)).
引用
收藏
页码：593 / 598
页数：6
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