Glycosylation of Stannyl Ceramides Promoted by Modified Montmorillonite in Supercritical Carbon Dioxide

被引：3

作者：

Antonio Morales-Serna, Jose ^{[1
]}

Nguyen, Bao N. ^{[2
]}

Garcia-Rios, Erendira ^{[3
]}

Gavino, Ruben ^{[3
]}

Cardenas, Jorge ^{[3
]}

Garcia de la Mora, Gustavo ^{[4
]}

机构：

[1] Univ Autonoma Metropolitana Iztapalapa, Dept Quim, Av San Rafael Atlixco 186, Ciudad De Mexico 09340, Mexico

[2] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

[3] Univ Nacl Autonoma Mexico, Inst Quim, Ciudad Univ, Ciudad De Mexico 04510, Mexico

[4] Univ Nacl Autonoma Mexico, Dept Quim Organ, Fac Quim, Ciudad Univ, Ciudad De Mexico 04510, Mexico

来源：

SYNTHESIS-STUTTGART | 2018年 / 50卷 / 03期

关键词：

glycosylation; beta-glycolipids; iGB3; supercritical carbon dioxide; montmorillonite; FLUID EXTRACTION; GREEN SOLVENTS; ACID; GLYCOSIDATION; CATALYSIS; SUGAR; CO2; GLYCOLIPIDS; SOLUBILITY; EFFICIENT;

D O I：

10.1055/s-0036-1591515

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The direct glycosylation of ceramides in supercritical carbon dioxide (scCO(2)) successfully proceeded to produce beta-glycolipids in high yield and with full stereoselectivity. The reaction is promoted by montmorillonite modified with a superacid (CF3SO3H). The value of this protocol was demonstrated in the efficient synthesis of isoglobotrihexosylceramide (iGB(3)).

引用

页码：593 / 598

页数：6

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