PECULIARITIES OF CRYSTALLIZATION PROCESS FOR Ge2Sb2Te5 THIN FILMS BY NANOSECOND SINGLE LASER PULSE

被引:0
作者
Lazarenko, P. [1 ]
Savelyev, M. [1 ]
Sherchenkov, A. [1 ]
Gerasimenko, A. [1 ]
Kozyukhin, S. [2 ,3 ]
Glukhenkaya, V. [1 ]
Polokhin, A. [1 ]
Shaman, Y. [1 ]
Vinogradov, A. [1 ]
机构
[1] Natl Res Univ Elect Technol, Zelenograd 124498, Russia
[2] RAS, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
[3] Natl Res Tomsk State Univ, Tomsk 634050, Russia
来源
CHALCOGENIDE LETTERS | 2018年 / 15卷 / 01期
关键词
Ge2Sb2Te5; Phase change material; Thin film; Laser irradiation; Crystallization; RAMAN-SCATTERING; GETE;
D O I
暂无
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Influence of nanosecond single laser irradiation on the surface morphology and structural transformation of the amorphous Ge2Sb2Te5 thin films was investigated. The destructions of the Ge2Sb2Te5 thin film after single ns pulse laser irradiation with fluence > 99.1 mJ/cm(2) were observed. The laser irradiation with fluence in the range from 74 to 77 mJ/cm(2) leads to crystallization of amorphous phase. Structure of as-deposited, annealed at 180 degrees C and irradiated thin films were examined by Raman spectroscopy. The intensity and shape of Raman spectra for irradiated (77 mJ/cm(2)) and annealed Ge2Sb2Te5 thin films are close to each other and correspond to fcc. However, the difference between the Raman spectra of thin film after nanosecond single laser irradiation and literature data for continuous-wave laser were observed.
引用
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页码:25 / 33
页数:9
相关论文
共 24 条
[1]   Raman scattering study of GeTe and Ge2Sb2Te5 phase-change materials [J].
Andrikopoulos, K. S. ;
Yannopoulos, S. N. ;
Kolobov, A. V. ;
Fons, P. ;
Tominaga, J. .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2007, 68 (5-6) :1074-1078
[2]   Phase transitions in thin Ge2Sb2Te5 chalcogenide films according to Raman spectroscopy data [J].
Avachev, A. P. ;
Vikhrov, S. P. ;
Vishnyakov, N. V. ;
Kozyukhin, S. A. ;
Mitrofanov, K. V. ;
Terukov, E. I. .
SEMICONDUCTORS, 2012, 46 (05) :591-594
[3]   Laser switching and characterisation of chalcogenides: systems, measurements, and applicability to photonics [Invited] [J].
Behera, Jitendra K. ;
Zhou, Xilin ;
Tominaga, Junji ;
Simpson, Robert E. .
OPTICAL MATERIALS EXPRESS, 2017, 7 (10) :3741-3759
[4]   Pulsed laser deposited GeTe-rich GeTe-Sb2Te3 thin films [J].
Bouska, M. ;
Pechev, S. ;
Simon, Q. ;
Boidin, R. ;
Nazabal, V. ;
Gutwirth, J. ;
Baudet, E. ;
Nemec, P. .
SCIENTIFIC REPORTS, 2016, 6
[5]  
Boy L., 2004, CHINESE PHYS, V13, P1947
[6]   Polymorphism of Amorphous Ge2Sb2Te5 Probed by EXAFS and Raman Spectroscopy [J].
Carria, E. ;
Mio, A. M. ;
Gibilisco, S. ;
Miritello, M. ;
d'Acapito, F. ;
Grimaldi, M. G. ;
Rimini, E. .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2011, 14 (12) :H480-H482
[7]   Isothermal crystallization of Ge2Sb2Te5 amorphous thin films and estimation of information reliability of PCM cells [J].
Kozyukhin, S. ;
Vorobyov, Yu. ;
Sherchenkov, A. ;
Babich, A. ;
Vishnyakov, N. ;
Boytsova, O. .
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2016, 213 (07) :1831-1838
[8]   Structural changes in doped Ge2Sb2Te5 thin films studied by Raman spectroscopy [J].
Kozyukhin, S. ;
Veres, M. ;
Nguyen, H. P. ;
Ingram, A. ;
Kudoyarova, V. .
10TH INTERNATIONAL CONFERENCE ON SOLID STATE CHEMISTRY, 2013, 44 :82-90
[9]   Peculiarities of Bi doping of Ge-Sb-Te thin films for PCM devices [J].
Kozyukhin, Sergey ;
Sherchenkov, Alexey ;
Babich, Alexey ;
Lazarenko, Petr ;
Huy Phuc Nguyen ;
Prikhodko, Oleg .
CANADIAN JOURNAL OF PHYSICS, 2014, 92 (7-8) :684-689
[10]   Valence band structures of the phase change material Ge2Sb2Te5 [J].
Lee, Dohyun ;
Lee, Sang Sun ;
Kim, Wondong ;
Hwang, Chanyong ;
Hossain, M. B. ;
Le Hung, Ngyuen ;
Kim, Hyojin ;
Kim, C. G. ;
Lee, Hangil ;
Hwang, Han Na ;
Hwang, Chan-Cuk ;
Lee, Tae-Yon ;
Kang, Younseon ;
Kim, Cheolkyu ;
Suh, Dong-Seok ;
Kim, Kijoon H. P. ;
Khang, Yoonho .
APPLIED PHYSICS LETTERS, 2007, 91 (25)