Fabrication of Fe/Fe3C@porous carbon sheets from biomass and their application for simultaneous reduction and adsorption of uranium(VI) from solution

被引：87

作者：

Wang, Xiangxue ^{[1
]}

Zhang, Shouwei ^{[1
,2
]}

Li, Jiaxing ^{[1
]}

Xu, Jinzhang ^{[2
]}

Wang, Xiangke ^{[1
,3
]}

机构：

[1] Chinese Acad Sci, Inst Plasma Phys, Hefei 230031, Peoples R China

[2] Hefei Univ Technol, Sch Mat Sci & Engn, Hefei 230031, Peoples R China

[3] King Abdulaziz Univ, Fac Engn, Jeddah 21589, Saudi Arabia

来源：

INORGANIC CHEMISTRY FRONTIERS | 2014年 / 1卷 / 08期

基金：

中国国家自然科学基金;

关键词：

ZERO-VALENT IRON; NANOSCALE ZEROVALENT IRON; GRAPHENE OXIDE NANOSHEETS; AQUEOUS-SOLUTION; CHLORINATED HYDROCARBONS; CARBOXYMETHYL CELLULOSE; HEXAVALENT CHROMIUM; TCE DECHLORINATION; H-2; EVOLUTION; REMOVAL;

D O I：

10.1039/c4qi00071d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Carbon-encapsulated Fe/Fe3C nanoparticles embedded in porous carbon sheets (Fe/Fe3C@PCS) were fabricated by a one step carbothermic reduction, using natural abundant biomass derivatives. Batch experimental results showed that Fe/Fe3C@PCS could effectively remove the radionuclide U(VI) from simulated wastewater in the presence of carbonate or calcium under laboratory conditions with reduced cost, improved activity and enhanced kinetics. Compared with activated carbon (AC), Fe/Fe3C@PCS is more efficient, and can remove U(VI) quantitatively at an initial concentration of up to 140 mg L-1. The major reaction pathway involved the reduction of U(VI) to the insoluble U(IV) species as identified by X-ray photoelectron spectroscopy (XPS) analysis. This study demonstrated the potential application of Fe/Fe3C@PCS as a low cost and effective remediation strategy for U-contaminated wastewater cleanup.

引用

页码：641 / 648

页数：8

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