Methanol-to-hydrocarbons:: catalytic materials and their behavior

被引：1331

作者：

Stöcker, M ^{[1
]}

机构：

[1] SINTEF Appl Chem, Dept Hydrocarbon Proc Chem, N-0314 Oslo, Norway

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 1999年 / 29卷 / 1-2期

基金：

欧盟地平线“2020”;

关键词：

methanol-to-hydrocarbons; MTO (methanol-to-olefin); MTG (methanol-to-gasoline); heterogeneous catalysis; review;

D O I：

10.1016/S1387-1811(98)00319-9

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The literature related to methanol-to-hydrocarbons (MTHC) technology over the past two decades has been reviewed, covering mainly the methanol-to-olefin (MTO) and methanol-to-gasoline (MTG) reactions. The work before around 1990 is briefly addressed, and the interested reader's attention is drawn to review papers published during the late 1980s summarizing the early work related to the methanol-to-hydrocarbons technology. This review focuses mainly on the chemistry and mechanism of those reactions including the catalysts involved and their behavior due to crystal size, pore architecture, acidity and reaction conditions, covering the time since around 1990. In a second review authored by F. Keil, the process related items: of methanol-to-hydrocarbons technology will be summarized and discussed in the light of kinetic and reaction technology aspects. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：3 / 48

页数：46

共 345 条

[1]

ABSID RPL, 1990, Patent No. 4919790

[2]

AGUAYO AT, 1994, CATLAYST DEACTIVATIO, P567

[3] Effects of metal impregnation on the activity, selectivity and deactivation of a high silica MFI zeolite when converting methanol to light alkenes [J].

AlJarallah, AM ;

ElNafaty, UA ;

Abdillahi, MM .

APPLIED CATALYSIS A-GENERAL, 1997, 154 (1-2) :117-127

[4]

ANDERSEN B, 1989, STUD SURF SCI CATAL, V49, P1193

[5] INSITU SOLID-STATE NMR-STUDIES OF THE CATALYTIC CONVERSION OF METHANOL ON THE MOLECULAR-SIEVE SAPO-34 [J].

ANDERSON, MW ;

SULIKOWSKI, B ;

BARRIE, PJ ;

KLINOWSKI, J .

JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (07) :2730-2734

[6] DIRECT OBSERVATION OF SHAPE SELECTIVITY IN ZEOLITE ZSM-5 BY MAGIC-ANGLE-SPINNING NMR [J].

ANDERSON, MW ;

KLINOWSKI, J .

NATURE, 1989, 339 (6221) :200-203

[7] C-13 AND H-1 MAGIC-ANGLE-SPINNING NMR-STUDIES OF THE CONVERSION OF METHANOL OVER OFFRETITE ERIONITE INTERGROWTHS [J].

ANDERSON, MW ;

OCCELLI, ML ;

KLINOWSKI, J .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (01) :388-392

[8] SOLID-STATE NMR-STUDIES OF THE SHAPE-SELECTIVE CATALYTIC CONVERSION OF METHANOL INTO GASOLINE ON ZEOLITE ZSM-5 [J].

ANDERSON, MW ;

KLINOWSKI, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (01) :10-16

[9]

[Anonymous], 1976, US Patent No, Patent No. 3979472

[10]

[Anonymous], METHANE CONVERSION

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