The First Uranyl Arsonates Featuring Heterometallic Cation-Cation Interactions with UVI=O-ZnII Bonding

被引：39
作者：
Tian, Tao [1 ]
Yang, Weiting [1 ]
Pan, Qing-Jiang [2 ]
Sun, Zhong-Ming [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Jilin, Peoples R China
[2] Heilongjiang Univ, Key Lab Funct Inorgan Mat Chem, Educ Minist, Sch Chem & Mat Sci, Harbin 150080, Peoples R China
来源：
INORGANIC CHEMISTRY | 2012年 / 51卷 / 20期
关键词：
CRYSTAL-STRUCTURES; URANIUM(VI) CARBOXYPHOSPHONATES; STRUCTURAL-CHARACTERIZATION; POLYOXOMETALATE CLUSTERS; HEXAVALENT URANIUM; COORDINATION; CHAIN; ION; FUNCTIONALIZATION; DIPHOSPHONATES;
D O I：
10.1021/ic3017479
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new uranyl arsonates, Zn(UO2)(PhAsO3)(2)L center dot H2O [L = 1,10-phenanthroline (1) and 2,2'-bipyridine (2)], have been synthesized by hydrothermal reactions of phenylarsonic acid, L, and ZnUO2(OAc)(4)center dot 7H(2)O. Single-crystal X-ray analyses demonstrate that these two compounds are isostructural and exhibit one-dimensional chains in which U-VI and Zn-II cations are directly connected by the yl oxygen atoms and additionally bridged by arsonate groups. Both compounds represent the first examples of uranyl arsonates with heterometallic cation-cation interactions.
引用
收藏
页码：11150 / 11154
页数：5
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